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Hara, Masamichi; Shinagawa, Katsuji; Omoto, Eijiro; Sunami, Kazuki; Deguchi, Seigo; Narumi, Hiroshi; Kojima, Kensuke; Azuma, Taichi; Takamatsu, Hideyuki; Nakao, Shinji; Harada, Mine

doi:10.1016/s0925-5710(98)00035-8

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2004

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“…Further, when exposed to heat, ductility and intensity of shell polymer also must be an important factor 2. From these points of view, as the monomer having gas barrier properties, acrylonitrile and methacrylonitrile are generally used as a polymerizable monomer 10–15. Japanese Patent Publication No.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and properties of thermoplastic expandable microspheres: The relation between crosslinking density and expandable property

Kawaguchi

Oishi

2004

J of Applied Polymer Sci

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A set of thermoplastic expandable microspheres was investigated with respect to their crosslinking density and expandable property. The crosslinking efficiencies of dipentaerythritol hexaacrylate in a set of thermoplastic expandable microspheres were measured. As expandable properties, expansion curves were measured by using a thermomechanical analyzer, and they also were shown by measuring the change of thickness of the coated compound consisting of ethylene-vinyl acetate copolymer resin emulsion and CaCO 3 with thermoplastic microspheres on paper. In view of the expansion ratio and heat resistance, as crosslinking density, a swelling ratio of about 20 -25 is needed to achieve optimum expansion without collapse and rupture of microspheres.

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Section: Introductionmentioning

confidence: 99%