Untitled

Time-Dependent Density Functional Theory Study of the Spectroscopic Properties Related to Aggregation in the Platinum(II) Biphenyl Dicarbonyl Complex

“…It was proposed that aggregation starts at certain limiting concentrations, depending on the donor number of the solvent. 6,7 The two possible interactions that would determine the type of aggregate were metal-metal interaction and π-π stacking. 1,8,9 Density functional theory (DFT)-calculated molecular orbital distributions have been very useful for the interpreta- tion of electrochemical and photochemical results for Ru-(II) complexes.…”

“…There are reports, however, that suggest a concentration and solvent dependence of the spectral behavior. It was proposed that aggregation starts at certain limiting concentrations, depending on the donor number of the solvent. , The two possible interactions that would determine the type of aggregate were metal−metal interaction and π−π stacking. ,, …”

Anodic electrochemical polymerization of complexes [Ni(Salpn-1,3)] and [Cu(Salpn-1,3)]

“…This coefficient reflects the rate of charge transfer and is a characteristic of the redox conductivity of the polymers [1]. The value of D ct depends on the polymer thickness, nature of the supporting electrolyte, and type of solvent [15].…”

High performance liquid chromatographic determination of platinum in blood and urine samples of cancer patients after administration of cisplatin drug using solvent extraction and N,N′-bis(salicylidene)-1,2-propanediamine as complexation reagent

“…It was found that the analytical procedure following complexation and extraction of platinum with ligand N,N -bis(salicylidene)-1,2-propanediamine (H 2 SA 2 pn) is simple, specific, convenient and cost-effective. The ligand H 2 SA 2 pn has been studied as a complexation reagent for platinum(II), copper(II), nickel(II), palladium(II), vanadium(IV), cobalt(II), iron(II) and uranium(VI) [31][32][33][34][35][36][37] and reverse phase HPLC determination and solvent extraction of copper(II), iron(II) and uranium(VI) [38]. However, the reagent has not been examined for the HPLC determination of platinum based drugs according to our best knowledge.…”