1998
DOI: 10.1023/a:1022456023875
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Cited by 4 publications
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“…is taken as a measure of the asymmetry, then it can be stated that IJ1 decreases significantly with increasing asymmetry of the Cu(NN),Cu framework (see Table 3). Triazole doubly bridged systems also show such a trend.14 In this case, the decrease in (4 was ascribed to a less effective overlap between the two copper magnetic orbitals, resulting from a larger asymmetry of the double diazene bridge (with possible relation to an enlargement of the N-Cu-N angle 15). General agreement exists that the dominant pathway for antiferromagnetic exchange in diazene-bridged systems is provided by (T bonding between copper d,Z_ .…”
Section: Magnetic Propertiesmentioning
confidence: 96%
“…is taken as a measure of the asymmetry, then it can be stated that IJ1 decreases significantly with increasing asymmetry of the Cu(NN),Cu framework (see Table 3). Triazole doubly bridged systems also show such a trend.14 In this case, the decrease in (4 was ascribed to a less effective overlap between the two copper magnetic orbitals, resulting from a larger asymmetry of the double diazene bridge (with possible relation to an enlargement of the N-Cu-N angle 15). General agreement exists that the dominant pathway for antiferromagnetic exchange in diazene-bridged systems is provided by (T bonding between copper d,Z_ .…”
Section: Magnetic Propertiesmentioning
confidence: 96%