The exceptional flooding event of the river Mulde in August 2002 led to an unexpected filling of the Goitzsche, an open‐pit lignite mining lake, within two days. Due to this exceptional situation, the groundwater table in the vicinity of the lake rose several meters in the area of Bitterfeld. Over the last 100 years, this region has been affected by a large‐scale contaminated aquifer of the former chemical industry complex Bitterfeld/Wolfen. Consequent to the rising groundwater level, the regional hydraulic situation and the groundwater flow direction changed entirely, as proven by hydraulic modelling results. Due to the heterogeneous aquifer conditions, the hydraulic importance was shown of a small scale channel‐fill at the bottom of the upper aquifer. This predominant geological structure evidently affects the groundwater flow direction indicated by the modelled path lines. The resulting pathways of the contaminants can be used for the identification of exposure routes related to areas of high ecological sensitivity. The monitoring of highly soluble groundwater contaminants (e.g. benzene, TCE, cis‐1,2‐DCE), close to the flooding event, shows (irregular patterns of increasing, as well as decreasing, concentration values of related groundwater contaminants. Until the present, no consistent regional pattern can be recorded in the shift of the distribution of the concentration induced by the flooding event. Local differences in the concentration values are obviously more related to small scale variations within the Quaternary aquifer in terms of hydraulic conductivity and higher residual concentration of the contaminated matrix sediments. The temporal effects of concentration values ca be traced back, by most of the organic compounds, to distinct observation wells within the monitored time span at the starting point before flooding.