Biodegradable
aerogels with flexibility and high strength are attractive
for construction, and acoustic and thermal insulation but are seriously
plagued by their flammability. Improving the flame retardancy of these
aerogels has been a hot topic of research and inorganic fillers, and
layered materials have been widely used for this purpose. However,
the poor interfacial compatibility of these fillers has affected the
processability and mechanical properties of the aerogels and reduced
their overall performance. In this study, we have used a completely
organic and sustainable polyelectrolyte complex (PEC) as a filler
for fabricating mechanically strong, sound-absorbing, and flame-retardant
poly(vinyl alcohol) (PVA) aerogels with the aid of an environmentally
friendly freeze-drying method. The noncovalent interactions between
the polymer and filler ensured excellent compatibility as well as
interfacial adhesion of the filler, and we could achieve a perfect
balance between the density and mechanical properties of the aerogels.
The prepared aerogels exhibited flexibility, good sound absorption
ability in the mid-frequency range, and excellent flame retardancy
(LOI ∼28%) with self-extinguishing behavior. A simple silane
modification endowed sticky hydrophobicity to the aerogels and further
enhanced their antifire properties. These sustainable multifunctional
aerogels could find a plethora of applications in real life, particularly
in buildings and structures as fire safety materials and sound insulators.