The work deals with the evaluation of applicability of reactor net models and different reaction mechanisms for the predictions of emission characteristics of aero-engine combustors operating both in diffusion and in homogeneous burning modes. It is shown that the accuracy of the calculations of emission indices for NO x , CO and unburned hydrocarbons (UHC) is dependent strongly on the applied reaction mechanisms. The computations exhibited that for the combustor operating in a diffusion mode the use of methane as a fuel, instead of kerosene, leads to decreasing NO x (by 35%) emission index, as well as to decreasing the CO and UHC emissions, while for the combustor with homogeneous combustion of fuel-lean mixture the use of methane as a fuel results in an increase of EINO x value (by a factor of 1.4) compared with kerosene-fuelled combustor.Reference to this paper should be made as follows: Starik, A.M., Kozlov, V.E., Lebedev, A.B. and Titova, N.S. (2014) 'Application of reactor net models for the simulation of gas-turbine combustor emissions', Int.