A 9,5-cyclogibberellin formed from a bromogibberellin-16-one derivative

Furber, Mark; Mander, LN; Patrick, Graham L.; Willis, A. C.

doi:10.1107/s0108270192003767

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2007

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“…It is used mainly to improve the rind quality of fruit (Coggins et al, 1969;Poling, 1991). Some crystal sructures of gibberellins are reported previously, such as gibberellin A20 (Komoda et al, 1968), gibberellin A4 trmethyl ester (Ellames et al, 1979), gibberellin A3 (Kutschabsky & Adam, 1983), 3-O-acetylgiberellin A3 (Hossain et al, 1988), gibberellin C (Thompson et al, 2000), 15crclogibberellin A9 (Furber et al, 1992), and gibberellin A15 (Nagata et al, 1971). We present here the structure of the title compound, (I).…”

Section: S1 Commentmentioning

confidence: 99%

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Gibberellin A4 monohydrate

Hua

Lin

et al. 2007

Acta Cryst E

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The title compond, C19H24O5·H2O, has two gibberellin A4 molecules and two water molecules in the asymmetric unit. The A and B rings have chair conformations, whereas the C and D rings have envelope conformations; the two rings which contain the lactone and carbonyl bridge adopt chair and envelope conformations. The crystal structure is established by O—H⋯O hydrogen bonds and supported by C—H⋯O hydrogen bonds.

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Section: S1 Commentmentioning

confidence: 99%

“…For related literature, see: Coggins et al (1969); Ellames et al (1979); Hossain et al (1988); Komoda et al (1968); Kutschabsky & Adam (1983); Thompson et al (2000); Furber et al (1992); Nagata et al (1971); Poling (1991).…”

Section: Related Literaturementioning

confidence: 99%