A bifunctional carbon catalyst with Cl and SO₃H groups for hydrolyzing furfural residue to levulinic acid

Abstract

BACKGROUND: Levulinic acid, an important platform compound, is extensively used in textiles, dyes, antifreeze, animal feed, solvents and food additives. However, the use of lignocellulosic biomass to produce levulinic acid is difficult because of poor accessibility to cellulose and low hydrolytic yield. Thus a viable hydrolysis strategy and a suitable catalyst must be developed.RESULTS: In this study, a bifunctional solid acid catalyst (HTC-SO 3 H) containing both cellulose binding sites ( Cl, COOH and OH) and catalytic sites ( SO 3 H) was prepared by a carbonization-grafting-oxidization method. X-ray photoelectron spectroscopy and Fourier transform infrared characterization confirmed the existence of Cl and the successful modification of the SO 3 H grafted hydrothermal carbon. The hydrogen bonds formed between cellulose and the binding sites ( Cl, OH and COOH) in the catalyst showed synergistic effects with the catalytic sites ( SO 3 H), leading to efficient hydrolysis of the furfural residue. A total of 74.81% (non-magnetic) and 70.18% (magnetic) levulinic acid yields were obtained after hydrolysis at 190 °C and 180 min in γ-valerolactone-H 2 O (1:1, v/v). Magnetic catalysts were synthesized using a co-precipitation method. Catalysts were recycled without any obvious reduction in catalytic activity. CONCLUSION: Using sucralose as a raw material, the as-synthesized bifunctional solid acid catalyst improved the accessibility to cellulose and increased levulinic acid yield. Moreover, the grafted SO 3 H formed by hydroxyl hydration condensation exhibited superior stability. This study provides a valuable strategy for the efficient hydrolysis of lignocellulosic biomass.

Structure and Catalytic Performance of Carbon-Based Solid Acids from Biomass Activated by ZnCl2

“…Carbon-based solid acid catalysts are amorphous materials characterized by a plethora of acidic catalytic centers. These centers facilitate the donation of hydrogen ions to substrates while maintaining structural integrity, thus enabling catalytic processes such as hydration [38]. The vertical and cross-sectional diameters of α-pinene are measured at approximately 0.84 nm and 0.77 nm, respectively.…”