in temperature-responsive hydrogels. [4,7] Although requiring careful consideration of heat transfer, such photothermal shape changes can provide rapid kinetics (at least for hydrogels with small dimensions, where mass transport is fast), nearly complete reversibility, and large volume changes.Directing the motion of micro-and nanoscale objects at an air/water interface is important from numerous perspectives, ranging from improving fundamental understanding of biological systems [8] to designing synthetic microrobots and swimmers. [9] Capillary and Marangoni forces can drive motion of sub-mm-scale objects, since these forces greatly exceed gravity or thermal energy on this scale. [10,11] Recently, reversible and programmed capillary assembly was demonstrated using temperature-responsive hydrogels with 3D shapes specified by spatial variations in swelling. [12] The shapes of the buckled particles distorted the contact line at the air-water interface, giving rise to capillary attraction between particles with a symmetry specified by the particle shape, and therefore the pattern of swelling. Another method to dynamically control capillary forces relied on the torques applied by rotating magnets. [13] However, these prior examples were limited to global changes in the state of the whole system, i.e., the temperature of water or the orientation of the magnetic field, thereby preventing control of single objects within a larger ensemble. While controlling the interactions and assemblies of such interfacially adsorbed objects with light is attractive for enabling high levels of spatiotemporal control, previous methods to drive motion through shape morphing have relied on patterning light on a length scale substantially smaller than the individual objects, [4,5,14] making this a challenging approach for dynamic or multicomponent systems.Here, we demonstrate spatial patterning of Au NPs as photothermal heaters embedded within temperature-responsive polymer hydrogels situated at an air/water interface, generating materials that exhibit reconfigurable capillary assembly and motion. We show that photochemical reduction [15] of a gold salt, using pendent benzophenone groups in a copolymer, enables high-resolution NP micropatterning within 2D sheets of temperature-responsive hydrogels. The resulting in-plane variations in Au NP concentration produce spatially nonuniform temperature profiles, and therefore hydrogel swelling under Patterning of nanoparticles (NPs) via photochemical reduction within thermally responsive hydrogel films is demonstrated as a versatile platform for programming light-driven shape morphing and materials assembly. Responsive hydrogel disks, containing patterned metal NPs, form characteristic wrinkled structures when illuminated at an air/water interface. The resulting distortion of the three-phase (air/water/hydrogel) contact lines induces capillary interactions between two or more disks, which are either attractive or repulsive depending on the selected pattern of light. By programming the shapes of t...