In nature, deep-sea fish featured with close-packed melanosomes
can remarkably lower light reflection, which have inspired us to design
ultrablack coatings for enhanced solar-to-thermal conversion. Herein,
a biomimetic ultrablack textile is developed enabled by the formation
of hierarchical polypyrrole (Ppy) nanospheres. The fabricated textile
exhibits prominently suppressed reflectance of lower than 4% and highly
enhanced absorption of up to 96%. Further experimental results and
molecular dynamics (MD) simulation evidence the formation process
of hierarchical nanospheres. Based on high-efficient solar-to-thermal
conversion, the biomimetic textile with desirable conductivity allows
the development of a salt-free solar evaporator, enabling a sustainable
seawater evaporation rate of up to 1.54 kg m–2 h–1 under 1 sun. Furthermore, the biomimetic hierarchical
textile exhibits good superhydrophobicity, enhanced photothermal property,
and high electrothermal conversion, demonstrating significant potential
in wearable thermal management (rescue vests) in water conditions.