Flexible counter
electrode (CE) plays an important role in portable quantum dot sensitized
solar cells (QDSCs). However, the present power conversion efficiency
(PCE) of bendable QDSC is rather limited partly due to the unsatisfactory
conductivity, flexibility, catalytic activity, and fabrication technique
of CE. In this work, flexible CEs composed of Cu
x
S and graphite paper (GP) are built and fabricated through
a facile successive ionic layer adsorption reaction (SILAR) method.
Through designing and optimizing of the surface property of GP, coverage,
and thickness of catalyst, excellently performed CEs are achieved
with the maximal PCE of 8.70% under one full sun illumination for
Zn–Cu–In–Se QDSCs. Further, fully flexible QDSCs
assembled with the as-prepared CEs and plastic photoanodes show a
high PCE of 2.45% under the same illumination.