2024
DOI: 10.1021/acs.inorgchem.4c01420
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A Bis-Cyclopentadienyl Ligand-Supported Di-Iron Trihydride Motif as a Synthon for Access to Heterobimetallic Trinuclear Complexes

Chung-Ching Tseng,
Yi-Wun Ding,
Zhong-Yue Chen
et al.

Abstract: Herein, we report the synthesis of a flexible bis-cyclopentadienyl ligand L (the doubly deprotonated form of H 2 L (1,3-bis(2,4-di-tert-butylcyclopentadienyldimethylsilyl)benzene)), demonstrating its ability to stabilize a series of di-iron hydrido complexes. Notably, this ligand facilitates the isolation of an unprecedented anionic cyclopentadienyl ligand-supported di-iron trihydride complex, LFe 2 (μ-H) 3 Li(THF) (2), functioning as a synthon for the [Fe 2 (μ-H) 3 ] − core and providing access to heterobimet… Show more

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