2013
DOI: 10.1039/c3dt51186c
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A bis(terpyridine)iron network polymer on carbon for a potential energy storage material

Abstract: A bis(terpyridine)iron network polymer was fabricated by electropolymerisation on a glassy carbon electrode. The modified electrode allowed high-speed charging and discharging with a minor capacity decay (only 5% after 3000 cycles at 1 V s(-1)).

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Cited by 7 publications
(4 citation statements)
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“…For instance, with phenylene or multi-phenylene bridges, the bis(terpyridyl) metal complex wires showed small E pa – E pc splitting. 39 However, the bis(terpyridyl) metal complex networks with a short metal–metal distance exhibit a large potential hysteresis in the electrochemical CV diagrams, 55 although both systems are constructed with the same metal complex unit.…”
Section: Resultsmentioning
confidence: 99%
“…For instance, with phenylene or multi-phenylene bridges, the bis(terpyridyl) metal complex wires showed small E pa – E pc splitting. 39 However, the bis(terpyridyl) metal complex networks with a short metal–metal distance exhibit a large potential hysteresis in the electrochemical CV diagrams, 55 although both systems are constructed with the same metal complex unit.…”
Section: Resultsmentioning
confidence: 99%
“…The present review summarises progress in metal complex molecular wires in the last decade, 17 covering fabrication procedures for linear and branched oligomer wires, characteristic intra-wire redox conduction, excellent long-range electron transport ability in the linear wire, and elucidation of the long-range This journal is © The Royal Society of Chemistry 2015 electron transport ability in the branched wire through an effective model. In addition, an ultra-long metal complex wire based bis(terpyridine)metal complex motif 18 is reported.…”
Section: Introductionmentioning
confidence: 99%
“…Potential step: 0.10 V (from 0.75 to 0.85 V vs. Ag + /Ag); 0.20 V (from 0.70 to 0.90 V); 0.40 V (from 0.60 to 1.00 V); 0.60 V (from 0.50 to 1.10 V); 0.80 V (from 0.40 to 1.20 V); 1.00 V (from 0.30 to 1.30 V). Adapted with permission from ref 18…”
mentioning
confidence: 99%
“…These metallo–polymeric films are enriched in photophysical and electrochemical assets, which unveil a whole new panorama of exciting solid-state applications in the field of electrochromism, electrocatalysis, sensors, and many more. Having said this, it becomes imperative to point out that only few of the existing reports have shed light on the potential applications of electropolymerized films as charge-storage memory devices. , Moreover, despite a profound backdrop on electropolymerization, only modest thought has been given to anodic polymerization of metal–polypyridyl complexes with pyrene moiety, so far . The pyrene-based complexes can offer robust and stable memory systems via a very convenient electropolymerization in a potential window ambient for metallo-chromophores.…”
Section: Introductionmentioning
confidence: 99%