A Blue Luminescent Starburst Molecule and Its Orange Luminescent Trinuclear PdII Complex: 1,3,5-tris(7-azaindol-1-yl)benzene (tabH) and [PdII3(tab)2Cl4]

Abstract

Alone, tabH luminesces blue (tabH=1,3,5‐tris(N‐7‐azaindolyl)benzene) but orange when complexed to PdII ions. Both the tabH ligand and the trinuclear complex 1 have been synthesized and characterized. The tab ligands in 1 function both as a chelating ligand and a bridging ligand, which leads to a linear arrangement of the three PdII ions.

Luminescent palladium complexes containing thioamide-based SCS pincer ligands

“…for C 18 H 23 ClN 2 PdS 2 : C, 45.67;H,4.90;N,5.92;Cl,7.49;S,13.55. Found: C,45.46;H,4.93;N,5.97;Cl,7.49;S,13.28%. 1 H NMR (400 MHz,2H,J = 7.6 Hz),7.11 (t,1H,J = 7.6 Hz), 4.13 (s-br, 8H), 1.79 (m-br, 12H).…”

Two novel interpenetrated zinc(II) and cadmium(II) coordination polymers based on 4-imidazole-benzoate: Syntheses, crystal structures and properties

“…The HIBA ligand was prepared by the method similar to that reported in ref. [13]. FT-IR spectra were recorded on a Bruker Vector22 FT-IR spectrophotometer using KBr disks.…”

Cyclopalladated complexes of 4-aryl-2,1,3-benzothiadiazoles: new emitters in solution at room temperature

“…According to the literature, the luminescence emission from Pd complexes can be attributed to ligand-localized (LC) states due to intraligand pp* transitions of the ligands, MLCT (monomeric) or MMLCT (dimeric) transitions. [50][51][52][53][54] The emission spectra were obtained using excitation wavelengths from the UV-Vis data. The measurements in dichloromethane were performed using excitation and emission slits of 5.0 nm/5.0 nm, respectively to the monomeric complexes.…”