A capillary micellar electrokinetic chromatography method for the stereoselective quantitation of bioallethrin in biotic and abiotic samples

García, María Concepción; Menéndez-López, Nuria; Boltes, Karina; Castro-Puyana, María; Marina, M. L.

doi:10.1016/j.chroma.2017.06.056

Cited by 10 publications

(3 citation statements)

References 30 publications

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“…Chen and co-workers [ 66 ] and Lucangioli and co-workers [ 54 ] independently developed two different methods for the separation of cis-trans isomers of sertraline using sodium deoxycholate and hydroxypropyl-β-CD and sodium cholate and hydroxypropyl-β-CD with sulfated β-CD, respectively. Garcia and co-workers used sodium deoxycholate with acetyl-β-CD for the chiral MEKC of bioallentrhin [ 67 ]. In the work of Chen and co-workers [ 68 ], the baseline enantioseparation of naphthalene-2,3-dicarboxaldehyde-tagged dipeptides alanylglutamine (ala-gln), tyrosylleucine (tyr-leu) and tyrosylphenylalanine (tyr-phe) was achieved by the combination of sodium deoxycholate and 2-hydroxypropyl-β-CD.…”

Section: Methods Developmentmentioning

confidence: 99%

“…Neutral amino acid biosignatures from Lake Mono were determined using a combination of sodium taurocholate and γ-CD [ 63 ]. The commercial formulations of insecticides cis -bifenthrin [ 55 ] and bioallenthrin [ 67 ] were determined using sodium cholate with heptakis (2,3,6-tri-O-methyl)-β-CD and sodium deoxycholate with acetyl-β-CD, respectively. Moreover, bioallenthrin degradation studies were also performed.…”

Section: Applications To Real Sample Analysesmentioning

confidence: 99%

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Bile Salts in Chiral Micellar Electrokinetic Chromatography: 2000–2020

Quirino

2021

Molecules

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Bile salts are naturally occurring chiral surfactants that are able to solubilize hydrophobic compounds. Because of this ability, bile salts were exploited as chiral selectors added to the background solution (BGS) in the chiral micellar electrokinetic chromatography (MEKC) of various small molecules. In this review, we aimed to examine the developments in research on chiral MEKC using bile salts as chiral selectors over the past 20 years. The review begins with a discussion of the aggregation of bile salts in chiral recognition and separation, followed by the use of single bile salts and bile salts with other chiral selectors (i.e., cyclodextrins, proteins and single-stranded DNA aptamers). Advanced techniques such as partial-filling MEKC, stacking and single-drop microextraction were considered. Potential applications to real samples, including enantiomeric impurity analysis, were also discussed.

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Section: Methods Developmentmentioning

confidence: 99%

Section: Applications To Real Sample Analysesmentioning

confidence: 99%

Bile Salts in Chiral Micellar Electrokinetic Chromatography: 2000–2020

Quirino

2021

Molecules

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“…As a chiral compound, pyrethroids usually have 4-8 stereoisomers [11]. Different isomers exhibit different insecticidal activities and selective degradation characteristics during microbial metabolism [12]. For example, αS-2S-fenvalerate can cause obvious bodily distortion and pericardial cysts in zebrafish, and the 96 h mortality of zebrafish induced by αS-2S-fenvalerate was 3.8 times higher than that of other enantiomers [13].…”

Section: Introductionmentioning

confidence: 99%

Novel Mechanism and Kinetics of Tetramethrin Degradation Using an Indigenous Gordonia cholesterolivorans A16

Guo

Huang

Pang

et al. 2021

IJMS

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Tetramethrin is a pyrethroid insecticide that is commonly used worldwide. The toxicity of this insecticide into the living system is an important concern. In this study, a novel tetramethrin-degrading bacterial strain named A16 was isolated from the activated sludge and identified as Gordonia cholesterolivorans. Strain A16 exhibited superior tetramethrin degradation activity, and utilized tetramethrin as the sole carbon source for growth in a mineral salt medium (MSM). High-performance liquid chromatography (HPLC) analysis revealed that the A16 strain was able to completely degrade 25 mg·L−1 of tetramethrin after 9 days of incubation. Strain A16 effectively degraded tetramethrin at temperature 20–40 °C, pH 5–9, and initial tetramethrin 25–800 mg·L−1. The maximum specific degradation rate (qmax), half-saturation constant (Ks), and inhibition constant (Ki) were determined to be 0.4561 day−1, 7.3 mg·L−1, and 75.2 mg·L−1, respectively. The Box–Behnken design was used to optimize degradation conditions, and maximum degradation was observed at pH 8.5 and a temperature of 38 °C. Five intermediate metabolites were identified after analyzing the degradation products through gas chromatography–mass spectrometry (GC-MS), which suggested that tetramethrin could be degraded first by cleavage of its carboxylester bond, followed by degradation of the five-carbon ring and its subsequent metabolism. This is the first report of a metabolic pathway of tetramethrin in a microorganism. Furthermore, bioaugmentation of tetramethrin-contaminated soils (50 mg·kg−1) with strain A16 (1.0 × 107 cells g−1 of soil) significantly accelerated the degradation rate of tetramethrin, and 74.1% and 82.9% of tetramethrin was removed from sterile and non-sterile soils within 11 days, respectively. The strain A16 was also capable of efficiently degrading a broad spectrum of synthetic pyrethroids including D-cyphenothrin, chlorempenthrin, prallethrin, and allethrin, with a degradation efficiency of 68.3%, 60.7%, 91.6%, and 94.7%, respectively, after being cultured under the same conditions for 11 days. The results of the present study confirmed the bioremediation potential of strain A16 from a contaminated environment.

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