A cascade catalytic system of photocatalytic oxidation based on Cu@PCN-222(Ni) and enzyme catalysis for the synthesis of chalcone compounds in one pot

Yu, Yuan; Liu, Chunxiu; Fan, Xinyue; Wei, Yunjie; Lin, Ru-De; Yao, Yao; Wang, Na; Yu, Xiao-Qi

doi:10.1016/j.jcat.2022.10.008

Cited by 8 publications

(2 citation statements)

References 45 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Ni Loading of MOF-545 and MOF-545(Cu) by the Impregnation Method (IM): Synthesis of Ni@MOF-545 IM and Ni@MOF-545(Cu) IM. The impregnation method was inspired by protocols previously reported for the synthesis of NP@MOF systems; 58 Ni Loading of MOF-545 by the Double-Solvent (DS) Method: Synthesis of Ni@MOF-545 DS. One hundred milligrams of synthesized MOF-545 were dispersed in 20 mL of n-pentane by sonication; 800 μL of 0.5 M Ni(NO 3 ) 2 •6H 2 O aqueous solution were then slowly added to the MOF suspension at a rate of 40 μL/min.…”

Section: Discussionmentioning

confidence: 99%

“…The impregnation method was inspired by protocols previously reported for the synthesis of NP@MOF systems; 100 mg of MOF-545 or MOF-545(Cu) were dispersed in 16 mL of methanol by sonication; and 162 mg of Ni(NO 3 ) 2 ·6H 2 O (0.56 mmol) were then added into the suspension and stirred for 1 h. The solvent was evaporated under vacuum, and the Ni@MOF-545 IM or Ni@MOF-545(Cu) IM solids were dried at 100 °C.…”

Section: Experimental Sectionmentioning

confidence: 99%

See 1 more Smart Citation

Zr-Based MOF-545 Metal–Organic Framework Loaded with Highly Dispersed Small Size Ni Nanoparticles for CO₂ Methanation

Chen,

Brubach,

Tran

et al. 2024

ACS Appl. Mater. Interfaces

View full text Add to dashboard Cite

We report the use of Zr-based metal−organic frameworks (MOFs) as supports to prepare catalysts with uniformly and highly dispersed Ni nanoparticles (NPs) for CO 2 hydrogenation into CH 4 . In the first step, we studied the MOF support under catalytic conditions using operando diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy, ex situ characterizations (PXRD, XPS, TEM, and EDX-element mapping), and DFT calculations. We showed that the high-temperature conditions undoubtedly confer a potential for catalytic functionality to the solids toward CH 4 production, while no role of the Cu could be evidenced. The MOF was shown to be transformed into a catalytically active material, amorphized but still structured with dehydroxylated Zr-oxoclusters, in line with DFT calculations. In the second step, Ni@MOF-545 catalysts were prepared using either impregnation (IM) or double solvent (DS) methods, followed by a dry reduction (R) route under H 2 to immobilize Ni NPs. The highest catalytic activity was obtained with the Ni@MOF-545 DS R catalyst (595 mmol CH4 g Ni −1 h −1 ) with 100% CH 4 selectivity and 60% CO 2 conversion after ∼3 h. The higher catalytic activity of Ni@MOF-545 DS R is a result of much smaller (∼5 nm) and better dispersed Ni NPs than in the IM sample (20−40 nm), the latter exhibiting sintering. The advantages of the encapsulation of Ni NPs by the DS method and of the use of a MOF-545-based support are discussed, highlighting the interest of designing yetunexplored Zr-based MOFs loaded with Ni NPs for CO 2 hydrogenation.

show abstract

Section: Discussionmentioning

confidence: 99%

Section: Experimental Sectionmentioning

confidence: 99%

Zr-Based MOF-545 Metal–Organic Framework Loaded with Highly Dispersed Small Size Ni Nanoparticles for CO₂ Methanation

Chen,

Brubach,

Tran

et al. 2024

ACS Appl. Mater. Interfaces

View full text Add to dashboard Cite

show abstract

Solvent-free oxidation of alcohols by a heterogeneous Fe3O4@SiO2-DTPA-Ru nanocatalyst

Jia,

Xu,

Cui

et al. 2024

Inorganic Chemistry Communications

View full text Add to dashboard Cite

Magnetic Ru nanocatalysts for green solvent-free oxidation reactions of aromatic alcohols

Jia,

Cui,

Yuan

et al. 2024

Journal of Organometallic Chemistry

View full text Add to dashboard Cite

A cascade catalytic system of photocatalytic oxidation based on Cu@PCN-222(Ni) and enzyme catalysis for the synthesis of chalcone compounds in one pot

Cited by 8 publications

References 45 publications

Zr-Based MOF-545 Metal–Organic Framework Loaded with Highly Dispersed Small Size Ni Nanoparticles for CO₂ Methanation

Zr-Based MOF-545 Metal–Organic Framework Loaded with Highly Dispersed Small Size Ni Nanoparticles for CO₂ Methanation

Solvent-free oxidation of alcohols by a heterogeneous Fe3O4@SiO2-DTPA-Ru nanocatalyst

Magnetic Ru nanocatalysts for green solvent-free oxidation reactions of aromatic alcohols

Contact Info

Product

Resources

About

A cascade catalytic system of photocatalytic oxidation based on Cu@PCN-222(Ni) and enzyme catalysis for the synthesis of chalcone compounds in one pot

Cited by 8 publications

References 45 publications

Zr-Based MOF-545 Metal–Organic Framework Loaded with Highly Dispersed Small Size Ni Nanoparticles for CO2 Methanation

Zr-Based MOF-545 Metal–Organic Framework Loaded with Highly Dispersed Small Size Ni Nanoparticles for CO2 Methanation

Solvent-free oxidation of alcohols by a heterogeneous Fe3O4@SiO2-DTPA-Ru nanocatalyst

Magnetic Ru nanocatalysts for green solvent-free oxidation reactions of aromatic alcohols

Contact Info

Product

Resources

About

Zr-Based MOF-545 Metal–Organic Framework Loaded with Highly Dispersed Small Size Ni Nanoparticles for CO₂ Methanation

Zr-Based MOF-545 Metal–Organic Framework Loaded with Highly Dispersed Small Size Ni Nanoparticles for CO₂ Methanation