This article deals with the analysis of backscattering at automatic target recognition (ATR) by ground-based radar located on rough terrain surfaces, using the properties of wave polarization. The purpose of the study is to examine and compare linear and circular polarized reflected waves, which can be described by decomposition theorems. Coherent decompositions (Pauli, Krogager, Cameron decomposition) are considered in the case of a rough terrain, for which the advantage of the Pauli decomposition has been shown. The article demonstrates an approach to the extraction of polarization signal backscattering data for two types of vehicles with different profiles. It is shown that the measurement results can be calibrated by a corner reflector that takes into account the properties of the ground surface, and further used for ATR based on supervised learning algorithms. The accuracy of object classification was 68.1% and 54.2% for the signal generated by linearly and elliptically polarized waves, respectively. Based on these results, we recommend using a linearly polarized wave as an object recognition mechanism. At the same time, any reflected depolarized wave significantly reshapes the structure due to the rotation of the object profile and the influence of a rough surface (vegetation fluctuations). This explains the low recognition accuracy in general.