Currently no sustainable, economical and scalable systems have been developed for the direct removal of roadside air pollutants at their source. Here we present a simple and effective air filtering technology: botanical biofiltration, and the first field assessment of three different botanical biofilter designs for the filtration of traffic associated air pollutants -NO2, O3 and PM2.5from roadside ambient air in Sydney, Australia. Over two six month research campaigns, we show that all of the tested systems filtered NO2, O3 and PM2.5 with average single pass removal efficiencies of up to 71.5%, 28.1% and 22.1% respectively. Clean air delivery rates of up to 121 m 3 /h, 50 m 3 /h and 40 m 3 /h per m 2 of active green wall biofilter were achieved for the three pollutants respectively, with pollutant removal efficiency positively correlated with their ambient concentrations. We propose that large scale field trials of this technology are warranted to promote sustainable urban development and improved public health outcomes. Key words: green infrastructure; green wall; living wall; air quality; traffic pollution; urban greening Highlights Botanical biofiltration of NO2, O3 and PM2.5 was achieved at roadside environments. NO2 was removed most efficiently, with a single pass removal efficiency of 71.5%. 3 Pollutant clean air delivery rates of 40-121 m /h per 1 m 2 plenum were achieved. All pollutant removal rates were positively correlated with ambient concentrations.