2024
DOI: 10.1002/ange.202412808
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A Clean One‐Pot Synthesis of Structurally Ordered Linear, Monocyclic, and Bicyclic Oligosiloxanes

Yoshihiro Shinohara,
Makiko Hatori,
Hiroshi Yamashita
et al.

Abstract: A highly selective cross‐coupling reaction between Si‐OAc (AcO = acetoxy) and Si‐OH compounds that generates unsymmetrical and symmetrical oligosiloxanes concurrent with the release of acetic acid has been developed. The high selectivity arises from the reactivity difference that depends on the varying number of acetoxy groups present, thus facilitating a clean one‐pot synthesis of oligosiloxanes. For instance, the reactions of di‐, tri‐, or tetraacetoxysilanes with silanols furnish acetoxy‐containing di‐ and … Show more

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