A relation for calculating the probability density function f t λ (ϕ) of the length scales of a passive concentration field in homogeneous turbulence has been obtained by consideration of the joint statistics of the concentration field and its gradient. The closed equation derived for f t λ (ϕ) has been solved numerically using the data of direct numerical modeling of homogeneous turbulence for the mean characteristics involved in the equation as the coefficients. The results obtained for different values of the Schmidt number have been compared.Introduction. Turbulence considerably intensifies the mixing and transfer of substances and heat in a flow. Many processes in the environment and in technical devices that are associated with flames, chemical reactions, and propagation of impurities would be completely impossible without efficient mixing. Although the history of study of turbulent mixing is rather long, its nature remains to be completely understood. We know of the equations using which one describes turbulent flows, but their numerical solution involves many difficulties.Direct numerical modeling of combined turbulent flows, which develops in connection with the progress made in computer technologies, cannot be used for problems of practical significance [1]. Therefore, one continues to develop statistical approaches with one method of averaging or another. One of them is the method of the probability density function (PDF) of different hydro-and thermodynamic parameters [2], which has been fruitfully used in studying reacting media.The advantages of the PDF method are primarily a simple and accurate representation of the influence of chemical sources on changes in the quantities sought and a lower consumption of computer time. Its main problem is that of modeling of the contribution of the process of fine-structure mixing of a scalar field of concentration (micromixing) to the general pattern of mixing. Micromixing is determined by the mechanism using which the scalar field brought to the state of "rough homogeneity" by the averaged flow and large vortices in the flow is broken by a statistically homogeneous turbulent velocity field down to the smallest turbulence scales due to the small-scale motion of the medium and next to the molecular level through molecular diffusion.The presence of all kinds of values of the concentrations and the existence of the entire range of scales create constantly interacting categories of turbulent mixing: the evolution of the length-scale range leads to a constant change in the boundary conditions for the action of molecular diffusion, thus influencing the rate of change in the concentration pulsations. The structure of the pulsation field is dependent on the small scales directly influencing the rate of dissipation of concentration pulsations more strongly than on large scales.Depending on the formulation of the problem, one selects the normalized temperature, the concentrations of the reactants or the inert impurity, the Schwab-Zel'dovich variables for turbulent flows ...