A co-crystal of 3-(3,5-dinitrobenzoyl)-1,1-dimethylthiourea andN,N-dimethyl-3,5-dinitrobenzamide

Abstract

Key indicators: single-crystal X-ray study; T = 123 K; mean (C-C) = 0.002 Å; R factor = 0.041; wR factor = 0.113; data-to-parameter ratio = 13.4.In the title compound, C 10 H 10 N 4 O 5 SÁC 9 H 9 N 3 O 5 , the amide groups of 3-(3,5-dinitro-benzoyl)-1,1-dimethyl-thiourea and N,N-dimethyl-3,5-dinitro-benzamide molecules are oriented at dihedral angles of 39.13 (8) and 55.97 (11) , respectively, to the attached benzene rings. In the crystal, the two molecules are linked by an N-HÁ Á ÁO hydrogen bond. Weak C-HÁ Á ÁO link the molecules into a sheet parallel to the bc plane. C-HÁ Á ÁS interactions also occur. Related literatureFor related structures, see: Saeed et al. (2010aSaeed et al. ( ,b, 2011Saeed et al. ( , 2012. ExperimentalCrystal data