A commentary on the self assembly and properties of a chiral titanium alkoxide cyclic trimer

Nanoporous TiO2 and WO3 Films by Anodization of Titanium and Tungsten Substrates: Influence of Process Variables on Morphology and Photoelectrochemical Response

“…Fluoride ions induce pitting of the nascent oxide layer on titanium by forming soluble fluoro complexes and are essential for nanopore formation. However, PEG is widely employed to modify interfacial behavior, 32 and D-mannitol (along with its derivatives) are known to form ligands with Ti to form soluble oligomers, 33 hence the choice of these two medium modifiers in the present work. Ammonium fluoride is soluble in glycerol under ultrasonication (entries 1-6, Table 1) but not in PEG 400 (entry 8, Table 1), and so a mixture of PEG (HO-(CH 2 -CH 2 -O) n -H) and water was used to dissolve NH 4 F in this case.…”

Synthesis, structure and functions of discrete titanium-based multinuclear architectures

“…Both "central" oxygen atoms of the ligands coordinated two Ti atoms in a bridging mode. A rather similar reaction starting from another tetraol was depicted later, and the authors deduced from NMR and MS data that a cyclic trinuclear Ti(IV) complex was obtained; [172] however, in the absence of X-ray structure, a linear complex similar to 58 is a hypothesis that cannot be excluded. It was reported that a quaterphenolato ligand imparted a helical twist to a trinuclear Ti and forced a bent structure (Ti...Ti...Ti angle of ca.…”

Isomers and conformers of complexes of Ti(OiPr)4with cyclopentane‐1,2‐dione: NMR study and DFT calculations

“…The structure of titanium/substrate/ligand complexes is a key factor determining the activity and selectivity of the catalytic processes. There have been several experimental and computational investigations dealing with the structure of titanium/ligand complexes and titanium/substrate/ligand clusters . Much less attention is paid to titanium/substrate complexes …”

“…There have been several experimental and computational investigations dealing with the structure of titanium/ligand complexes [15][16][17][18][19][20] and titanium/substrate/ligand clusters. [21][22][23][24][25][26][27] Much less attention is paid to titanium/substrate complexes. [28,29] The complexes of 1,2-cyclopentanedione 1 (Scheme 1) with VOCl 3 have been studied.…”