From the use of a pinhole camera placed under a water tank, which was proposed almost 100 years ago, to the application of modern digital cameras mounted with sophisticated fisheye lenses, acquisition methods for capturing hemispherical photographs undergone vigorous research and development. Over the past few decades, such photographs have been extensively used in evaluating energy and environmental aspects in urban contexts. In this review article, the advantages, limitations, and challenges of the various methods of acquiring photographs are described and compared. This involves both the devices themselves and the software tools. Several methods of direct acquisition of hemispheric photographs involving digital cameras, smartphones, the use of drones for photographs at elevations, and the application of thermal imaging technologies are discussed in detail. Indirect methods for generating hemispheric photographs are also discussed, highlighting the use of images from applications such as Google Street View (GSV). Based on a review of technical literature, several applications in energy and the environment that use information from hemispheric photographs as an analysis tool are presented and discussed. Among others, the following are discussed: the quantification of solar radiation potential; the assessment of indicators of local temperature and level of thermal comfort for pedestrians in urban areas; indoor and outdoor daylighting; and air and light pollution. Finally, several potential future research directions for the use of hemispherical photographs in built environments are discussed. These include advances in image processing, use of thermal imaging, solar potential assessment of solar-powered vehicles, applications of drone-mounted hemispherical photography, and fisheye videos.