A comparison of electrooxidation of phenol on boron doped diamond and mixed metal oxide anodes

Abstract

Phenolic compounds are widespread in wastewater from various industries. Since the phenols are potentially carcinogenic for humans and hazardous for the environment, their presence in wastewater raises concerns. In this paper electrooxidation process was used for treatment of synthetical prepared wastewater containing phenol. Initial phenol concentration in wastewater was 50 mg/L with addition of different supporting electrolytes (NaCl, Na2SO4, H2SO4). The treatment was performed in a batch electrochemical reactor at constant current density of 20 mA/cm2. Boron doped diamond (BDD) and mixed metal oxide (MMO) anode materials were examined, and stainless steel was used as cathode. Phenol concentration before and after treatment was determined by standard spectrophotometric method with 4-aminoantipyrine, while transformation products were identified by different chromatographic methods. Experiments have shown that the treatment is very efficient and with low energy consumption, wherein the phenol removal efficiency mostly depends on the duration of treatment and the type of supporting electrolyte.