2015
DOI: 10.1016/j.cattod.2015.01.036
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A comparison of hierarchical Pt@CeO2/Si–Al2O3 and Pd@CeO2/Si–Al2O3

Abstract: a b s t r a c tA comparison of catalytic and adsorption properties for Pt@CeO 2 /Si-Al 2 O 3 (1-wt% Pt and 9-wt% CeO 2 ) and Pd@CeO 2 /Si-Al 2 O 3 (1-wt% Pd and 9-wt% CeO 2 ) core-shell catalysts indicates that the CeO 2 shell is stable for Pd but not for Pt. Following calcination at 773 K, Pt@CeO 2 /Si-Al 2 O 3 exhibits water-gas-shift (WGS) rates in 3% H 2 O and CO that are similar to rates found on conventional Pt/CeO 2 , implying that there is good contact between the Pt and CeO 2 phases, even at the relat… Show more

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Cited by 8 publications
(8 citation statements)
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“…Agglomerates of PdO and CeO 2 nanoparticles were observed in our previous work, although a different method of synthesis was employed . Similar core‐shell structures have been reported in other works …”
Section: Discussionsupporting
confidence: 86%
“…Agglomerates of PdO and CeO 2 nanoparticles were observed in our previous work, although a different method of synthesis was employed . Similar core‐shell structures have been reported in other works …”
Section: Discussionsupporting
confidence: 86%
“…39 At higher temperature, formates are further converted and become intermediates in the catalytic process, 39 while sintering of Pt is considered the main reason for catalyst deactivation. 38 In order to hinder Pt sintering, hierarchical Pt@CeO 2 /Si-Al 2 O 3 samples were prepared from self-assembled core-shell nanoparticles, 40 obtaining stable catalytic activity aer pre-treatment of the catalyst at 500 C. Differently from Pt, Pd@CeO 2 /Si-Al 2 O 3 demonstrates a fast decrease of the catalytic activity, 40,41 mainly because of an electronic inuence due to reduced CeO 2Àx and the partial occlusion of Pd nanoparticles within CeO 2Àx crystallites. 41 To overcome these problems, Pd@CeO 2 /MWCNT hybrid materials have been synthesized, observing that the balance between the organic and inorganic components favors their electronic interaction, nally leading to stable catalytic performances in the WGSR.…”
Section: Wgsr Activitymentioning
confidence: 99%
“…Over the past several decades, different types of catalysts have been developed for low-temperature methane combustion . These include noble metal-based (e.g., Pd, Pt, and Au , ), metal oxide-based (e.g., CuO, Co 3 O 4 , CeO 2 , and MnO x ), perovskite, spinel, and hexa-aluminate catalysts . Among them, Pd-based catalysts are some of the best for methane conversion .…”
Section: Introductionmentioning
confidence: 99%