1970
DOI: 10.1007/bf00183657
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A comparison of reaction rate models for the fracture of solids

Abstract: The application of the theory of reaction rates to the fracture of solids is reviewed. Four different models are compared and shown to exhibit three basic differences in formulation. The evidence appears to favor bond rupture, as opposed to bond slippage, as the basic mechanism leading to fracture of certain polymer systems. It is shown that other differences in the models cannot be resolved by a comparison with existing experimental data.

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Cited by 37 publications
(12 citation statements)
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“…This essential tail property, along with the Weibull distribution itself, was first derived in 1928 by Fisher and Tippett (1928) from the stability postulate of extreme value statistics of a set of independent, identically distributed, random variables. Of course, the RVEs in a material are not perfectly statistically independent, but the stability postulate can also be justified for correlated random systems (such as percolation models, Bazant, 2000Bazant, , 2002van der Hofstad and Redig, 2006) using renormalization group methods, which homogenize the system recursively up to a scale (of the RVE) where correlations become negligible. Aside from the assumption of independence, however, the FisherTippett argument has nothing to do with physics per se, and for a long time it has not been clear whether the power-law tail would apply only for probabilities so small (e.g.…”
Section: Strength Statisticsmentioning
confidence: 98%
“…This essential tail property, along with the Weibull distribution itself, was first derived in 1928 by Fisher and Tippett (1928) from the stability postulate of extreme value statistics of a set of independent, identically distributed, random variables. Of course, the RVEs in a material are not perfectly statistically independent, but the stability postulate can also be justified for correlated random systems (such as percolation models, Bazant, 2000Bazant, , 2002van der Hofstad and Redig, 2006) using renormalization group methods, which homogenize the system recursively up to a scale (of the RVE) where correlations become negligible. Aside from the assumption of independence, however, the FisherTippett argument has nothing to do with physics per se, and for a long time it has not been clear whether the power-law tail would apply only for probabilities so small (e.g.…”
Section: Strength Statisticsmentioning
confidence: 98%
“…The offset approach [as seen in Eq. 1, but also revised elsewhere (Henderson et al, 1970;Bartenev, 1973)] considers that the applied stresses decrease the energy barrier for bond breakage. Some simulation studies (Gagnon et al, 2001) support this interpretation, but they also give a very different mechanistic description of crack propagation, following the coalescence of voids forming ahead of the crack tip; a model that seems to be at odds with the most recent experimental investigation (Wiederhorn et al, 2013a).…”
Section: Application To Experimental Datamentioning
confidence: 99%
“…20, which neglects any bond reformation process, was confirmed by experiments on several metals and polymers. With the advent of fracture mechanics, this approach was subsequently applied to model crack propagation rate [29,30].…”
Section: Fracture Modelsmentioning
confidence: 99%