“…A number of defect detection techniques based on non-linear behavior can be defined according to the particular aspect that is considered, among the features resulting from the non-linear characteristic of the examined system; one can distinguish between methods that detect the presence of higher order harmonics [6][7][8], methods that analyze the frequency shift of resonances [9,10], vibro-acoustic modulation methods [5,11], and frequency mixing methods, which highlight the production of non-linear combinations of harmonic components that have been generated due to different phenomena or propagation modes [12,13]. In the first case, the response is analyzed to detect the presence of higher order harmonics: e.g., in [6], it is shown how non-linearity due to the presence of damages manifests itself as sideband components in the spectrum of the received signal, while in [8], a technique based on pulse compression and the scalar subtraction method are compared under the same experimental conditions to highlight their respective sensitivities: a laboratory test experiment on mortar samples is performed to compare their ability to detect spectral components due to early damage in samples showing a non-linear response. To give a quantitative idea of the improvement that can be achieved in terms of resolution by considering non-linear phenomena, we report that in [8], the experimental results carried out on concrete bar adopting a swept sine signal, whose center frequency is 55 kHz, allowed the detection of an U-shaped notch in the middle of the bar, whose dimension in the direction of propagation is approximately λ/12, i.e., allowing a range resolution at least 3 or 4 times higher than that of the usual ultrasound techniques.…”