This paper makes a comparative study
on the normal diffusion flame
(NDF) and inverse diffusion flame (IDF) characteristics of dimethyl
ether (DME) in microgravitational spherical diffusion flame geometry
by simulations with detailed fuel chemistry and a transport model.
It is found that there always existed two combustion modes (i.e.,
hot flame and cool flame) in either NDF or IDF condition. The combustion
progress of hot flames was controlled by diffusive mixing, while that
of cool flames was controlled by low-temperature competing kinetics.
The cool-flame structure dynamics were far away from the chemical
equilibrium. The low-temperature branching rate of DME was positively
dependent on the oxygen level, while its termination rate was enhanced
with the increasing temperature. Being rather distinct from the NDF
counterpart, DME IDFs had the oxygen-enriched combustion feature in
either hot- or cool-flame condition. Furthermore, DME hot-flame extinction
was induced by thermal radiative loss, while the cool-flame extinction
was induced especially by the decrease of the low-temperature branching
rate. Compared with hot NDFs, it would be of less effectiveness to
control the hot IDF combustion process by positive measures. However,
combustion in the latter configuration was much more stable than the
former. In either NDF or IDF geometry, the cool-flame chemistry could
help to extend the fuel flammability range considerably, and the two-reaction-zone
structure of cool flame was responsible for cool-flame stability.
In addition, the IDFs had much better ignition performance than the
NDF counterpart.