Zn 2 GeO 4 nanorods were successfully synthesized by a simple hydrothermal method. The composition, morphology, and optical properties of as-synthesized Zn 2 GeO 4 samples were characterized by X-ray diffraction, scan electron microscopy, and UV-vis diffuse reflectance spectra. The photocatalytic properties of Zn 2 GeO 4 nanorods were evaluated by the reduction of Cr(VI) and oxidation of organic pollutants in aqueous solution. The effects of solution pH on Cr(VI) reduction by Zn 2 GeO 4 nanorods were studied in detail. The results indicated that the efficiency of Cr(VI) reduction was highest at pH 5.96. Moreover, Zn 2 GeO 4 nanorods also showed excellent photocatalytic ability for the oxidation of organic pollutants such as rhodamine B and 4-nitrophenol.