The Almonacid de la Cuba section, located in the Iberian Range, in central-eastern Spain, contains an outstanding record of the Pliensbachian-Toarcian boundary (Early Jurassic). Four ammonite assemblages, characterized respectively by the presence of Pleuroceras, Canavaria, Dactylioceras (Eodactylites) and Dactylioceras (Orthodactylites) have been distinguished. The base of the Toarcian is located at level CU35.2, based on the first occurrence of Dactylioceras. The presence of Boreal and Mediterranean taxa allows correlation between both bioprovinces. Magnetostratigraphy shows the most complete record of reversals of the Earth magnetic field for the base of Toarcian. The onset of the positive δ 13 C excursion which has been found in the Toarcian of several sections in Europe has been recorded. Average paleotemperatures for the latest Pliensbachian Spinatum Zone was about 12.5°. Seawater temperature rise during the lowermost Toarcian, reaching average temperatures of 16.7°C at the Tenuicostatum Zone. The 87 Sr/ 86 Sr curve fits with the LOWESS calibration curve.