A Complex Cyanide of Trivalent Molybdenum

Young, Ralph C.

doi:10.1021/ja01343a018

Cited by 54 publications

(23 citation statements)

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“…[11] (60 mg in 3 mL H 2 O at the bottom). Compound 2 was prepared by pumping on single-crystal samples of 1 under a dynamic vacuum at 125 8C for 8 h followed by further pumping for 5 h at 150 8C using the "outgas" function of a gas adsorption analyzer.…”

Section: Methodsmentioning

confidence: 99%

Crystal‐to‐Crystal Transformation of Magnets Based on Heptacyanomolybdate(III) Involving Dramatic Changes in Coordination Mode and Ordering Temperature

et al. 2012

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Section: Methodsmentioning

confidence: 99%

Crystal‐to‐Crystal Transformation of Magnets Based on Heptacyanomolybdate(III) Involving Dramatic Changes in Coordination Mode and Ordering Temperature

et al. 2012

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“…However, Young (295) has succeeded in preparing a compound of formula &MO(CN),(H~O)~ which presumably contains cyanide ion coordinated to molybdenum(II1). However, Young (295) has succeeded in preparing a compound of formula &MO(CN),(H~O)~ which presumably contains cyanide ion coordinated to molybdenum(II1).…”

Section: Ions Of Elements Of Group V I B Chromium(ii)mentioning

confidence: 99%

Rates and Mechanisms of Substitution in Inorganic Complexes in Solution.

Taube¹

1952

Chem. Rev.

408

217

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“…Ed. 2005, 44, 7742;(c) Li, D.-F.; Parkin, S.; Wang, G.-B. ; Yee, G. T.; Clérac, R.; Wernsdorfer, W.; Holmes, S. M. An S = 6 Cyanide-Bridged Octanuclear Fe Exhibits Slow Relaxation of the Magnetization.…”

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confidence: 99%

A Three‐Dimensional Mn^II‐[Mo^III(CN)₇]^4– Ferrimagnet Containing Formate as a Second Bridging Ligand

et al. 2018

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of main observation and conclusion Self-assembly of the [Mo(CN) 7 ] 4anion and the Mn 2+ ion in the aqueous solution containing ammonium formate results in a new coordination polymer, {(NH 4 ) 3 [(H 2 O)Mn 3 (HCOO)][Mo(CN) 7 ] 2 ·4 H 2 O} n . Single crystal X-ray analysis revealed a very complicated three-dimensional (3D) framework, where both the [Mo(CN) 7 ] 4and the formate anions act as bridges between the Mn II centers. Magnetic measurements revealed that this compound displays ferrimagnetic ordering below 70 K. Competing antiferromagnetic interactions between the spin carriers might lead to spin frustration and non-linear alignment of the magnetic moments. Specifically, this compound is the first mixed [Mo(CN) 7 ] 4-/HCOO bridged molecule magnet. 20 www.cjc.wiley-vch.de

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A Complex Cyanide of Trivalent Molybdenum

Cited by 54 publications

References 0 publications

Crystal‐to‐Crystal Transformation of Magnets Based on Heptacyanomolybdate(III) Involving Dramatic Changes in Coordination Mode and Ordering Temperature

Crystal‐to‐Crystal Transformation of Magnets Based on Heptacyanomolybdate(III) Involving Dramatic Changes in Coordination Mode and Ordering Temperature

Rates and Mechanisms of Substitution in Inorganic Complexes in Solution.

A Three‐Dimensional Mn^II‐[Mo^III(CN)₇]^4– Ferrimagnet Containing Formate as a Second Bridging Ligand

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A Complex Cyanide of Trivalent Molybdenum

Cited by 54 publications

References 0 publications

Crystal‐to‐Crystal Transformation of Magnets Based on Heptacyanomolybdate(III) Involving Dramatic Changes in Coordination Mode and Ordering Temperature

Crystal‐to‐Crystal Transformation of Magnets Based on Heptacyanomolybdate(III) Involving Dramatic Changes in Coordination Mode and Ordering Temperature

Rates and Mechanisms of Substitution in Inorganic Complexes in Solution.

A Three‐Dimensional MnII‐[MoIII(CN)7]4– Ferrimagnet Containing Formate as a Second Bridging Ligand

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A Three‐Dimensional Mn^II‐[Mo^III(CN)₇]^4– Ferrimagnet Containing Formate as a Second Bridging Ligand