A complex lead-free (Na, Bi, Ba)(Ti, Fe)O 3 single phase perovskite ceramic with a high energy-density and high discharge-efficiency for solid state capacitor applications

Mishra, Anupam; Majumdar, Bhaskar; Ranjan, Rajeev

doi:10.1016/j.jeurceramsoc.2017.01.036

Cited by 92 publications

(37 citation statements)

References 29 publications

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“…Meanwhile, the energy efficiency slightly increases and then nearly remains constant (~65%) with increases in the field. Figure D provides a comparison of the recoverable energy density in representative lead‐free candidate materials in recent years . It can be seen that the ceramics in this study have a relatively high W re value of 1.75 J/cm 3 , which is nearly 2.5 times higher than that of Nb‐modified BiFeO 3 ‐BaTiO 3 ceramics .…”

Section: Resultsmentioning

confidence: 83%

Novel bismuth ferrite‐based lead‐free ceramics with high energy and power density

et al. 2018

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In this work, a new lead-free relaxor ferroelectric 0.60BiFeO 3 -0.34BaTiO 3 -0.06Sr(Al 0.5 Nb 0.5 )O 3 (BBFTO-SAN) ceramic was prepared via the conventional solid-state reaction method. High recoverable energy density (1.75 J/ cm 3 ) and efficiency (81%) were achieved, which is superior to some other lead-free ceramics. Good thermal stability in a wide temperature range (30-120°C) was also investigated in this system. Moreover, we first studied the charge-discharge performance of bulk BFO-based energy storage ceramics and obtained an ultra-high power density p D (~57 MW/cm 3 ) as well as a large current density value of~1353 A/cm 2 . Consequently, all the results indicate that this ceramic is a promising lead-free candidate for energy storage materials. K E Y W O R D Sbismuth ferrite-based, charge-discharge, energy storage, lead-free ceramics

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Section: Resultsmentioning

confidence: 83%

Novel bismuth ferrite‐based lead‐free ceramics with high energy and power density

et al. 2018

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“…To fully illustrate the superior energy storage performances of the 0.85NBT-0.06BT-0.09ASN ceramic, comparison of W rec ~ ƞ between 0.85NBT-0.06BT-0.09ASN ceramic and the above lead-free ceramics is shown in Fig. 8b [12,15,29,43,56,71,[76][77][78][79][80][81][82][83][84][85][86][87]. It is obvious that the 0.85NBT-0.06BT-0.09ASN ceramic simultaneously exhibits high W rec and ƞ as relative to most of the lead-free energy storage ceramics.…”

Section: Resultsmentioning

confidence: 99%

High energy storage density and efficiency with excellent temperature and frequency stabilities under low operating field achieved in Ag0.91Sm0.03NbO3-modified Na0.5Bi0.5TiO3-BaTiO3 ceramics

Chen

et al. 2020

J Mater Sci: Mater Electron

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Ag 0.91 Sm 0.03 NbO 3-modified Na 0.5 Bi 0.5 TiO 3-BaTiO 3 ceramics (0.94−x)Na 0.5 Bi 0.5 TiO 3-0.06BaTiO 3-x(Ag 0.91 Sm 0.03)NbO 3 (x = 0, 0.03, 0.06, and 0.09) were prepared by solid-state reaction method. The structural, dielectric, and energy storage properties of the ceramics were systematically studied. Our results indicate that all ceramics exhibit pure perovskite structure with dense microstructure. All the elements in the ceramic are homogeneously distributed. The sample with the doping level x = 0.09, possesses good temperature stability of the dielectric constant (Δε′/ε′ 150 °C ≤ ± 15%) and low dielectric loss (< 0.02) over a wide temperature of 84-318 °C. A large energy storage density value of W rec = 2.12 J/cm 3 , high efficiency of ƞ = 83% under a low electric field of 18 kV/mm, as well as excellent temperature/frequency stabilities were simultaneously achieved in the sample. This work provides a viable way to design high energy storage performance lead-free ceramics operating at low fields.

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“… Recoverable energy density of selected lead-free relaxor systems from 2010 to 2020 [ 97 , 100 , 103 , 122 , 123 , 141 , 197 , 206 , 207 , 208 , 209 , 210 , 211 , 212 , 213 , 214 , 215 , 216 , 217 , 218 , 219 , 220 , 221 , 222 , 223 , 224 , 225 , 226 , 227 , 228 , 229 , 230 , 231 , 232 , 233 , 234 , 235 , 236 , 237 , 239 , 240 , 256 , 257 , 258 , 259 , 260 , 261 , 262 , 263 ]. Note: BNT—Bismuth Sodium Titanate, BST—Barium Strontium Titanate and BZT—Barium Zirconium Titanate.…”

Section: Figurementioning

confidence: 99%

Strategies to Improve the Energy Storage Properties of Perovskite Lead-Free Relaxor Ferroelectrics: A Review

et al. 2020

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Electrical energy storage systems (EESSs) with high energy density and power density are essential for the effective miniaturization of future electronic devices. Among different EESSs available in the market, dielectric capacitors relying on swift electronic and ionic polarization-based mechanisms to store and deliver energy already demonstrate high power densities. However, different intrinsic and extrinsic contributions to energy dissipations prevent ceramic-based dielectric capacitors from reaching high recoverable energy density levels. Interestingly, relaxor ferroelectric-based dielectric capacitors, because of their low remnant polarization, show relatively high energy density and thus display great potential for applications requiring high energy density properties. In this study, some of the main strategies to improve the energy density properties of perovskite lead-free relaxor systems are reviewed, including (i) chemical modification at different crystallographic sites, (ii) chemical additives that do not target lattice sites, and (iii) novel processing approaches dedicated to bulk ceramics, thick and thin films, respectively. Recent advancements are summarized concerning the search for relaxor materials with superior energy density properties and the appropriate choice of both composition and processing routes to match various applications’ needs. Finally, future trends in computationally-aided materials design are presented.

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A complex lead-free (Na, Bi, Ba)(Ti, Fe)O 3 single phase perovskite ceramic with a high energy-density and high discharge-efficiency for solid state capacitor applications

Cited by 92 publications

References 29 publications

Novel bismuth ferrite‐based lead‐free ceramics with high energy and power density

Novel bismuth ferrite‐based lead‐free ceramics with high energy and power density

High energy storage density and efficiency with excellent temperature and frequency stabilities under low operating field achieved in Ag0.91Sm0.03NbO3-modified Na0.5Bi0.5TiO3-BaTiO3 ceramics

Strategies to Improve the Energy Storage Properties of Perovskite Lead-Free Relaxor Ferroelectrics: A Review

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