A Computer Modeling Study of Perfect and Defective Silver (111) Surfaces

Abstract

Density functional theory calculations of the ideal and defective (111) surfaces of silver have shown that although the perfect surface shows very little atomic relaxation the introduction of vacancies, adatoms, and step edges on the surface leads to significant bond distortions in the near-defect regions. The defective surfaces are not significantly less stable than the perfect (111) surface and the average calculated surface energy of 0.49 eV per surface atom agrees well with the experimental value of 0.55 eV/atom. Electron density contour plots show delocalization along the surface compared to the bulk metal, while a more gradual decline of the electron density in the defect areas compared to the perfect surface leads to a more level electronic structure of the defective surfaces than their atomic structure. The formation energies of surface vacancies and adatoms with respect to gaseous silver atoms are +3.20 eV and -2.03 eV, respectively, while the introduction of a step edge on the surface costs 0.42 eV per edge atom with respect to the planar surface. Adsorption of an adatom at the step edge releases 2.50 eV and the lower-coordinated edge sites, rather than the terrace sites of the planar (111) surface, are thus energetically preferred sites for further silver growth. Segregation of vacancies from the bulk material to the (111) surface is calculated to be exothermic at -0.18 eV per vacancy and recombination of a surface vacancy with a surface adatom will release 1.81 eV per vacancy/adatom pair.

Structural evolution of pentacene on a Ag(110) surface

“…We first calculate one pentacene molecule adsorbed on Ag͑110͒ substrate with different layers of Ag atoms by MMϩ force field, and consider six layers of silver atoms for this calculation. 27 Then, we simplify the calculation process and calculate a single pentacene molecule adsorbed on Ag͑110͒ with three possible adsorption modes, standing up, lying sideways, and lying flat ͓see Fig. 4͑c͔͒.…”

In situ X-ray analysis under controlled potential conditions: An innovative setup and its application to the investigation of ultrathin films electrodeposited on Ag(111)

“…Experimental works carried out on surfaces with a small roughness show an undetectable contraction of the surface layer [39,40]. However a recent theoretical work [41] predicts a contraction of about 5-7% in the case of silver adatoms. Then in the case of the Ag(1 1 1) the contraction of the top layer strongly depends on the surface roughness.…”

Thermally Selective Formation of Subsurface Oxygen in Ag(111) and Consequent Surface Structure

“…Ag(111) surfaces exhibit a variety of different surface reconstructions induced by adsorbed oxygen (O ad ) (5,9), along with several other oxide species (10)(11)(12)(13)(14)(15)(16). The primary motivation to study the O/Ag(111) system is silver's importance as an industrial partial oxidation catalyst (11,17). Virtually all ethylene oxide (EO), an important intermediate in the production of plastics, glycols, and polyester, is produced by the partial oxidation of ethylene to EO over Ag catalysts (18).…”