A concise water-solvent synthesis of highly effective, durable, and eco-friendly flame-retardant coating on cotton fabrics

Zhang, Fengxiu; Gao, Wei‐Wei; Jia, Yaling; Lü, Yi; Zhang, Guang‐Xian

doi:10.1016/j.carbpol.2018.05.085

Cited by 48 publications

(16 citation statements)

References 34 publications

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“…At the same time, non-combustible gases such as NH 3 , H 2 O and CO 2 will dilute O 2 and gaseous fuel concentration in the combustion zone and exhibit good flame retardancy. As shown in Figure 13 , the flame retardant mechanism of PLA/HABP-DOPO blends should be the synergistic flame retardancy of solid phase and gas phase [ 38 , 39 ].…”

Section: Resultsmentioning

confidence: 99%

Effect of a Novel Flame Retardant on the Mechanical, Thermal and Combustion Properties of Poly(Lactic Acid)

et al. 2020

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Poly(lactic) acid (PLA) is one of the most promising biobased materials, but its inherent flammability limits its applications. A novel flame retardant hexa-(DOPO-hydroxymethylphenoxy-dihydroxybiphenyl)-cyclotriphosphazene (HABP-DOPO) for PLA was prepared by bonding 9,10-dihydro-9-oxy-10-phosphaphenanthrene-10-oxide (DOPO) to cyclotriphosphazene. The morphologies, mechanical properties, thermal stability and burning behaviors of PLA/HABP-DOPO blends were investigated using a scanning electron microscope (SEM), a universal mechanical testing machine, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), limiting oxygen index (LOI), vertical burning (UL-94) and a cone calorimeter test (CCT). The LOI value reached 28.5% and UL-94 could pass V-0 for the PLA blend containing 25 wt% HABP-DOPO. A significant improvement in fire retardant performance was observed for PLA/HABP-DOPO blends. PLA/HABP-DOPO blends exhibited balanced mechanical properties. The flame retardant mechanism of PLA/HABP-DOPO blends was evaluated.

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Section: Resultsmentioning

confidence: 99%

Effect of a Novel Flame Retardant on the Mechanical, Thermal and Combustion Properties of Poly(Lactic Acid)

et al. 2020

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“…The final product showed a high limiting oxygen index (about 43%) which was maintain to about 33.4% after 50 laundering cycles that confirmed its high flame-retardant stability. Moreover, the toxicity results of this fabric revealed no toxicity against humans and the environment (Zhang et al 2018).…”

Section: Flame-retardant Textilesmentioning

confidence: 89%

Functionalization of polymers and nanomaterials for water treatment, food packaging, textile and biomedical applications: a review

et al. 2020

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The inert nature of most commercial polymers and nanomaterials results in limitations of applications in various industrial fields. This can be solved by surface modifications to improve physicochemical and biological properties, such as adhesion, printability, wetting and biocompatibility. Polymer functionalization allows to graft specific moieties and conjugate molecules that improve material performances. In the last decades, several approaches have been designed in the industry and academia to graft functional groups on surfaces. Here, we review surface decoration of polymers and nanomaterials, with focus on major industrial applications in the medical field, textile industry, water treatment and food packaging. We discuss the advantages and challenges of polymer functionalization. More knowledge is needed on the biology behind cell–polymer interactions, nanosafety and manufacturing at the industrial scale.

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“…Other studies examined the flame-retardant properties of cellulose textiles by incorporating the N-P-based flame retardants ATEPAHP (ammonium salt of tetraethylene pentaamine heptamethylphosphonate), ACMPEP (ammonium salt of cholamine (methylene phosphonic acid) ethylene-organic phosphate acid), AATMP (ammonium amino trimethylene phosphonate), and AMHMPA (ammonium salt of melamine hexa(methylphosphonic acid), respectively (Zhang et al 2018a;Huang et al 2019;Tian et al 2019). The vertical flame tests demonstrated that the pristine cellulose textiles burned fully, but damage lengths of 4.8 cm, 3.8 cm, 3.0 cm, and 5.3 cm were obtained for the cellulose textiles treated with ATEPAHP, ACMPEP, AATMP, and AMHMPA, respectively (Tables 1 and 2).…”

Section: Cotton Fabrics Treated With N P-based Non-polymeric Organic Compoundsmentioning

confidence: 99%

Cotton-based flame-retardant textiles: A review

Islam

Ven

2021

BioRes

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Biodegradable textiles made from cellulose, the most abundant biopolymer, have gained attention from researchers, due to the ease with which cellulose can be chemically modified to introduce multifunctional groups, and because of its renewable and biodegradable nature. One of the most attractive features required for civilian and military applications of textiles is flame-retardancy. This review focuses on various methods employed for the fabrication of cellulose-based flame-retardant cotton textiles along with their developed flame-retardant properties over the last few years. The most common method is to merge N, S, P, and Si-based polymeric, non-polymeric, polymeric/non-polymeric hybrids, inorganic, and organic/inorganic hybrids with cellulose to fabricate flame-retardant cotton textiles. In these studies, cellulose was chemically bonded with the flame-retardants or in some cases, cotton textiles were coated by flame-retardants. The flame-retardant properties of the cotton textiles were investigated and determined by various methods, including the limiting oxygen index (LOI), the vertical flame test, thermal gravimetric analysis (TGA), and by cone calorimetry. This review demonstrates the potential of cellulose-based flame-retardant textiles for various applications.

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A concise water-solvent synthesis of highly effective, durable, and eco-friendly flame-retardant coating on cotton fabrics

Cited by 48 publications

References 34 publications

Effect of a Novel Flame Retardant on the Mechanical, Thermal and Combustion Properties of Poly(Lactic Acid)

Effect of a Novel Flame Retardant on the Mechanical, Thermal and Combustion Properties of Poly(Lactic Acid)

Functionalization of polymers and nanomaterials for water treatment, food packaging, textile and biomedical applications: a review

Cotton-based flame-retardant textiles: A review

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