1933
DOI: 10.1135/cccc19330527
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A contribution to the knowledge of the liquid junction potentials. Part II

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Cited by 6 publications
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“…A situation where it is not desirable to use the ligand in excess occurs in the case of stepwise formation of very stable complexes ML, (i = 1, 2.....p): For ligand to metal ratios greater than p the species MLp will be formed almost exclusively and only the pth equilibrium could be studied accordingly. Current-potential curves obtained under conditions of nearly stoichiometric or substoichiometric ligand to metal ratio may have shapes which are different from those expected for reversible systems (J) as has been shown for polarography (9,10) and cyclic voltammetry (CV) (11,12).…”
mentioning
confidence: 88%
“…A situation where it is not desirable to use the ligand in excess occurs in the case of stepwise formation of very stable complexes ML, (i = 1, 2.....p): For ligand to metal ratios greater than p the species MLp will be formed almost exclusively and only the pth equilibrium could be studied accordingly. Current-potential curves obtained under conditions of nearly stoichiometric or substoichiometric ligand to metal ratio may have shapes which are different from those expected for reversible systems (J) as has been shown for polarography (9,10) and cyclic voltammetry (CV) (11,12).…”
mentioning
confidence: 88%
“…For these simulations, at time zero, two different and initially homogenous electrolytes (named Solution 1 and Solution 2) were modeled to come into contact, and the total potential drop for these free diffusion liquid junctions are presented in Table 2. Chloupek et al (1933); 4. Grahame and Cummings (1950).…”
Section: Liquid-junctions Potentialsmentioning
confidence: 99%