A Convenient Method for the Generation of a Disulfur Monoxide Equivalent and Its Reaction with Diazoalkanes to Yield Dithiirane 1-Oxides

Reaction between Dithiirane 1-Oxides and a Platinum(0) Complex

“…Treatment of dithiirane 1‐oxides 9a − e 11k with 3 , carried out in dichloromethane at 0 °C, produced (sulfenato− thiolato)platinum(II) complexes 7a , 7b , 7d , and 7e in high yields (Scheme ). The structures of the complexes were supported by their 31 P NMR spectroscopic data, summarized in Table 1.…”