2004
DOI: 10.1016/s1386-9477(04)00017-7
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A convenient phase transfer route for Ag nanoparticles

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Cited by 8 publications
(9 citation statements)
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“…The carbonyl stretch vibration in carboxylic acids, ketones, and aldehydes is observed at around 1760 cm −1 (42-44). The absorption peak at about 1612 cm −1 can be attributed to the asymmetric stretching vibration of COO−, while the band at 1420 cm −1 is a result of the symmetric stretching vibration of COO− and the stretching vibration of C−O (44)(45)(46). Moreover, the band within 1200-1000 cm −1 is dominated by ring vibrations overlapped with stretching vibrations of (C−O−H) side groups and the (C−O−C) glycoside band vibration.…”
Section: Ft-ir Resultsmentioning
confidence: 99%
“…The carbonyl stretch vibration in carboxylic acids, ketones, and aldehydes is observed at around 1760 cm −1 (42-44). The absorption peak at about 1612 cm −1 can be attributed to the asymmetric stretching vibration of COO−, while the band at 1420 cm −1 is a result of the symmetric stretching vibration of COO− and the stretching vibration of C−O (44)(45)(46). Moreover, the band within 1200-1000 cm −1 is dominated by ring vibrations overlapped with stretching vibrations of (C−O−H) side groups and the (C−O−C) glycoside band vibration.…”
Section: Ft-ir Resultsmentioning
confidence: 99%
“…Although tannic acid has been previously utilized as a reducing agent in the presence of additional stabilizers [48] or as both the reducing and stabilizing agent [49,50] but the reaction times reported lie between half to two and a half hours at 80 ∘ C, whereas the particle sizes reported are >15 nm. The crucial difference between the study conducted by Sivaraman et al [16] and the earlier reports is that the pH of the tannic acid solution was adjusted prior to the addition of metal salt.…”
Section: Silver Nanoparticles Synthesized Using Tannic Acidmentioning
confidence: 99%
“…In view of these metals being noble and also environmental concerns, organic based reductants have been widely used in this practice. These include trisodium citrate (C6H5O7Na3), 14,22,23) formaldehyde (CH2O), 8,12) polyethylene glycol (C2n 2H4n 6 On 2 ), 24) glucose (C6H12O6), 22) ascorbic acid (C6H8O6), 25) tannic acid (C34H28O21), 26) polyvinylapyrrolidone (PVP: C6H9NO), 14,22,27) polyvinylalcohol (PVA; (C2H4O)n), 22,27) oleyl amine (C18H37N), 11) and many more. In addition, the literature mentions a host of other organic reductants.…”
Section: B Choice Of Reductantsmentioning
confidence: 99%
“…The so called "inverse micelle method" is frequently used in the synthesis of nano-metal particles, and utilizes such a two-phase system. 22,26) As depicted in Fig 2, a group of metal ions dissolved in a water droplet are surrounded by organic surfactants which have a special affinity with the metal ions. These metal ions can be negative, as in the case of AuCl4or positive as in the case of Ag inside the droplets.…”
Section: F Reduction With Organic Phasementioning
confidence: 99%