Tetrahedron Letters

1995

DOI: 10.1016/0040-4039(95)01675-8

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A convenient preparation of allylic amines

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Cited by 11 publications

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An Efficient Synthesis ofN-Phosphorylated Azadienes, Primary (E)-Allylamines, and β-Amino-Phosphane Oxides and -Phosphonates from β-Functionalized Oxime Derivatives

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et al. 1998

Eur. J. Org. Chem.

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No abstract

An Efficient Synthesis ofN-Phosphorylated Azadienes, Primary (E)-Allylamines, and β-Amino-Phosphane Oxides and -Phosphonates from β-Functionalized Oxime Derivatives

¹

,

²

,

³

et al. 1998

Eur. J. Org. Chem.

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No abstract

Desulfonylation Reactions

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²

2009

Organic Reactions

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The use of sulfones in organic chemistry, acting as an auxiliary group, is still a very important synthetic strategy, especially for the formation of carbon‐carbon single and double bonds. Once the synthetic objective is achieved, the sulfone gruop is usually removed from the molecule. This removal most commonly involves a reductive desulfonylation process with either replacement of the sulfone by hydrogen, or a process that results in the formation of a carbon‐carbon double bond when a β‐hydroxy or β‐alkoxy sulfone is employed. This chapter is devoted to the replacement of the sulfone group by a hydrogen (reductive desulfonylation reactions), and reductive elimination reactions of Julia‐type substrates (Julia‐Lythgoe olefination process). The chapter addresses the full scope, generality, limitations, and synthetic applications of these reactions. The literature through most of 2007 is covered.

2‐( p ‐Methoxyphenylamino)ethyl phenyl sulfone

Ho¹,

2006

Fieser and Fieser's Reagents for Organic Synthesis

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