2022
DOI: 10.1177/17475198221090908
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A convenient route to mono-trans polyunsaturated free fatty acids

Abstract: Trans unsaturated fatty acids in humans may be originated both from dietary supplementation and from an endogenous free-radical-catalyzed cis−trans isomerization of fatty acid residues in naturally occurring cis lipids. The latter process affords geometrical isomers and the polyunsaturated fatty acid mono-trans isomers were demonstrated to be connected with stress conditions in living organisms. Synthesis of mono-trans polyunsaturated fatty acid is useful for analytical and biological research, and in this cas… Show more

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“…The chemical composition of biodiesel, which is a complex mixture of many fatty esters with varied chain lengths and degrees of saturation, affects its viscosity [193]. The viscosity of the biodiesel increases due to the production of free fatty acids, isomerization at the double bond positions, often from cis to trans, and the formation of products with a larger molecular weight [194]. The addition of antioxidants leads to a reduction in viscosity because antioxidants inhibit the autooxidation of biodiesel, which is the primary source of free fatty acids, and other products with a higher molecular weight.…”
Section: Source Of Antioxidantsmentioning
confidence: 99%
“…The chemical composition of biodiesel, which is a complex mixture of many fatty esters with varied chain lengths and degrees of saturation, affects its viscosity [193]. The viscosity of the biodiesel increases due to the production of free fatty acids, isomerization at the double bond positions, often from cis to trans, and the formation of products with a larger molecular weight [194]. The addition of antioxidants leads to a reduction in viscosity because antioxidants inhibit the autooxidation of biodiesel, which is the primary source of free fatty acids, and other products with a higher molecular weight.…”
Section: Source Of Antioxidantsmentioning
confidence: 99%