In the past years, there has been an emerging number of studies on estimating the passenger demand in urban environments based on social media and cellular data. However, the study of the travel behavior at the individual level and the relation between social media activity and the activity/mobility patterns of users has received limited attention. To rectify this, this study examines Twitter data for unveiling the relations between geo-tagged Tweets and Twitter user sentiments, and the respective activity types performed in the real-world. In this work we try to find common patterns between users' Twitter activity and their actual mobility/activity patterns with the aim to provide some generalizations that can help to understand and model the travel behavior of users. This is achieved with the development of educated rules and probabilistic models that can predict the mobility transfers of users between different activities based solely on social media data. The validity of our generalizations is validated with the use of 4-month Twitter data from London. Only active Twitter users have been selected to study in deep the relations between social media activities/sentiments and the activity types performed in the real-world. Although our generalizations are case study-specific, they demonstrate that it is possible to extract the activity and mobility behavior of users with the use of social media and offer a first step in this direction.