A couple of Co(II) enantiomers constructed from semirigid lactic acid derivatives

Xu, Zhong-Xuan; Ma, Yulu; Zhang, Li‐Shuang; Zhang, Jian

doi:10.1016/j.inoche.2016.10.013

Cited by 17 publications

(3 citation statements)

References 50 publications

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“…Since the end of the 20th century, considerable attention has been paid to synthesis and characterization of novel coordination polymers (CPs) as well as metal-organic framework (MOFs) with fascinating structures and diverse functions [1][2][3][4][5][6][7][8]. An important feature is that the choice of appropriate ligands plays a very crucial role in the construction of CPs with specific structures, which promoted chemists to design new ligands and study their coordination chemistry [9].…”

Section: Introductionmentioning

confidence: 99%

Selective and Recyclable Sensing of Aqueous Phase 2,4,6-Trinitrophenol (TNP) Based on Cd(II) Coordination Polymer with Zwitterionic Ligand

et al. 2018

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A novel coordination polymer, {[Cd4(Dccbp)4]·H2O} (1) (Dccbp = 3,5-dicarboxy-1-(3-carboxybenzyl)pyridin-1-ium) was synthesized under hydrothermal conditions by a zwitterionic organic ligand and characterized by single crystal X-ray diffraction, infrared spectrum (IR), thermogravimetric analysis (TG), powder X-ray diffraction (PXRD) and luminescence. Complex 1 with a pyridine cation basic skeleton has the potential to serve as the first case of a luminescent material based on the zwitterionic type of organic ligand for selective, sensitive, and recyclable sensing of 2,4,6-trinitrophenol in the aqueous phase.

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Section: Introductionmentioning

confidence: 99%

Selective and Recyclable Sensing of Aqueous Phase 2,4,6-Trinitrophenol (TNP) Based on Cd(II) Coordination Polymer with Zwitterionic Ligand

et al. 2018

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“…They have attracted this attention not only because of their diverse architectures, but also because of their potential luminescent sensor applications for detecting cations [1,2], anions [3,4], small molecules [5], gases and vapors [6], biomolecules [7], temperature [8,9], and so on [10,11]. Compared with other luminescent sensors, Ln-CPs based luminescent sensing materials have been a rapidly developing area due to their outstanding merits such as high surface area, easily designed crystal structures, stable frameworks, and permanent porosity, as well as exposed active sites [12][13][14].…”

Section: Introductionmentioning

confidence: 99%

“…Considering the extensive application and potential harm of acetone, it is urgent to develop new luminescent sensors to detect it. To date, only a few CPs have been reported for the sensing of acetone [20][21][22][23], most of which were constructed by d 10 transition metal ions (Zn and Cd) and π-conjugated ligands, whereas coordination polymer materials based on lanthanide ions have been rarely published [24]. The advantages of those lanthanide materials over the transition metal luminescent materials include the sharp and strong emissions, large stokes shifts, high quantum yields, and long luminescence lifetimes, which originate from f-f transitions of lanthanide ions [25].…”

Section: Introductionmentioning

confidence: 99%

Lanthanide Coordination Polymers as Luminescent Sensors for the Selective and Recyclable Detection of Acetone

Wang¹,

Tang³

2017

Crystals

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Abstract:Three new isostructural lanthanide coordination polymers {[Ln(L) 2 ·2H 2 O]·Cl·4H 2 O}, Ln = La (LaL 1), Tb (TbL 2), Eu (EuL 3), L = 4-carboxy-1-(4-carboxybenzyl)pyridinium, have been synthesized under hydrothermal conditions and characterized by single crystal X-ray diffraction, IR, TG, PXRD, and luminescence. The solid-state luminescence properties of those Ln-CPs were investigated, realizing the zwitterionic ligand (L) is an excellent antenna chromophore for sensitizing both Tb 3+ and Eu 3+ ions. We utilized TbL 2 as a representative chemosensor to consider the potential luminescence sensing properties in different solvent suspension, which has the potential to serve as the first case of a luminescent Ln-CP material based on the zwitterionic type of organic ligand for selective and recyclable sensing of acetone in methanol solution.

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Two Pairs of Homochiral Coordination Polymers with Helices Based on Semi‐rigid Lactic Acid Ligands

Liu

et al. 2017

Zeitschrift anorg allge chemie

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Utilizing semirigid lactic acid derivatives (R)‐H2CBA and (S)‐H2CBA as chiral ligands, two pair of homochiral coordination polymers formulated as [Zn((R)‐CBA)(1,4‐DIB)]·H2O (1‐D), [Zn((S)‐CBA)(1,4‐DIB)]·H2O (1‐L), [Co((R)‐CBA)(1,4‐DIB)]·H2O (2‐D) and [Co((S)‐CBA)(1,4‐DIB)]·H2O (2‐L) were prepared under solvothermal reaction condition. Single X‐ray diffraction study reveals that all the complexes are comprised of three kinds of helical chains, which are constructed by corresponding metal ions, CBA2– ligands, and/or 1,4‐DIB ligands. Moreover, some physical characteristics, such as PXRD, thermal stabilities, solid‐state circular dichroism (CD), luminescent and magnetic properties are also investigated.

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A couple of Co(II) enantiomers constructed from semirigid lactic acid derivatives

Cited by 17 publications

References 50 publications

Selective and Recyclable Sensing of Aqueous Phase 2,4,6-Trinitrophenol (TNP) Based on Cd(II) Coordination Polymer with Zwitterionic Ligand

Selective and Recyclable Sensing of Aqueous Phase 2,4,6-Trinitrophenol (TNP) Based on Cd(II) Coordination Polymer with Zwitterionic Ligand

Lanthanide Coordination Polymers as Luminescent Sensors for the Selective and Recyclable Detection of Acetone

Two Pairs of Homochiral Coordination Polymers with Helices Based on Semi‐rigid Lactic Acid Ligands

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