A determination of the crystal structure of CdNi

Structures of NiCd6+δ(−0.32 ≤ δ ≤ 0.35) – a γ-brass related phase, and NiCd1+δ(0 ≤ δ ≤ 0.05) – a Ti2Ni type phase in the nickel–cadmium system

“…NiCd 1+d (0 ¡ d ¡ 0.05) showed the same symmetry Fd3 ¯m (227) as reported by Critchley et al 18 Measurement details, atomic coordinates, site occupancy factors and equivalent isotropic displacement parameters are in Tables 3 and 4. Further details of the crystal structure determination are given in the ESI 3 (Fig.…”

“…14,16 The information about NiCd was first reported by Lihl and Buhl was confirmed later by many investigators. [16][17][18] The crystal structure of NiCd is shown to be face centered cubic (cF96, g-carbide type) with a lattice parameter of 11.39(1) Å. The…”

Mg8Rh4B — A new type of boron stabilized Ti2Ni structure

“…In rare cases, the 16d position filled by the A component in Ti 2 Ni type is occupied by the M component and the total composition changes to AM. This derivative from the Ti 2 Ni structure type is called NiCd [1]. The main feature of the Ti 2 Ni structure type is the ability to incorporate non-metal elements like H, C, N, O [2,3].…”

Crystal-chemical model of atomic interactions. 3. Convex polyhedra with regular faces

“…One more ZP was found in the CdNi structure (Critchley & Jeffery, 1965) which possesses complexes of three types (Fig. 13).…”