A Diglyme Adduct of Tin(IV) Chloride Formed on Drying Aromatic Solvents by the Benzophenone Ketyl/Potassium Metal Method

The interaction of SnBr, and KSCN in methanol solution has been studied by '19Sn NMR at149 MHz and -30 "C. Evidence was obtained for the existence of both the cis and trans isomeric forms of SnBr4*2MeOH. A painvise additivity model for chemical s h e was used to explain the observed peaks and many of the possible species, SnBrn(NCS),-,3MeOH, [SnBr,(NCS),-,.MeOH]-and [SnBr,(NCS),-,]*-, ( n = 0-4), and their isomeric forms were identified and shown to exist simultaneously in solution in complex equilibria.In some cases 1"Sn-'4N coupling was observed. The implications for possible synthesis of these types of compounds and the necessity for measurement at high field are discussed.

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Use of high‐field ¹¹⁹Sn NMR and the pairwise additivity model for chemical shifts in the identification of complexes in the SnBr₄–KSCN–MeOH system

Blunden

Cusack

Gillies

1986

Magnetic Reson in Chemistry

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Syntheses and spectroscopic studies of inorganic tin and organotin derivatives of 1-(4-methylphenylimino)methyl]-2-naphthol. Crystal structure of chlorotrimethyl 1-(4-methylphenylimino)methyl]-2-naphtholTin(IV)

et al. 1995

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Syntheses and characterization of some inorganic tin and organotin(IV) adducts of N-p-methoxyphenylpyridine-2-carbaldimine

et al. 1995

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A Diglyme Adduct of Tin(IV) Chloride Formed on Drying Aromatic Solvents by the Benzophenone Ketyl/Potassium Metal Method

Cited by 4 publications

References 7 publications

Use of high‐field ¹¹⁹Sn NMR and the pairwise additivity model for chemical shifts in the identification of complexes in the SnBr₄–KSCN–MeOH system

Use of high‐field ¹¹⁹Sn NMR and the pairwise additivity model for chemical shifts in the identification of complexes in the SnBr₄–KSCN–MeOH system

Syntheses and spectroscopic studies of inorganic tin and organotin derivatives of 1-(4-methylphenylimino)methyl]-2-naphthol. Crystal structure of chlorotrimethyl 1-(4-methylphenylimino)methyl]-2-naphtholTin(IV)

Syntheses and characterization of some inorganic tin and organotin(IV) adducts of N-p-methoxyphenylpyridine-2-carbaldimine

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A Diglyme Adduct of Tin(IV) Chloride Formed on Drying Aromatic Solvents by the Benzophenone Ketyl/Potassium Metal Method

Cited by 4 publications

References 7 publications

Use of high‐field 119Sn NMR and the pairwise additivity model for chemical shifts in the identification of complexes in the SnBr4–KSCN–MeOH system

Use of high‐field 119Sn NMR and the pairwise additivity model for chemical shifts in the identification of complexes in the SnBr4–KSCN–MeOH system

Syntheses and spectroscopic studies of inorganic tin and organotin derivatives of 1-(4-methylphenylimino)methyl]-2-naphthol. Crystal structure of chlorotrimethyl 1-(4-methylphenylimino)methyl]-2-naphtholTin(IV)

Syntheses and characterization of some inorganic tin and organotin(IV) adducts of N-p-methoxyphenylpyridine-2-carbaldimine

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Product

Resources

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Use of high‐field ¹¹⁹Sn NMR and the pairwise additivity model for chemical shifts in the identification of complexes in the SnBr₄–KSCN–MeOH system

Use of high‐field ¹¹⁹Sn NMR and the pairwise additivity model for chemical shifts in the identification of complexes in the SnBr₄–KSCN–MeOH system