2022
DOI: 10.1002/ange.202202140
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A Dinuclear Metallobridged Super Aryl‐Extended Calix[4]pyrrole Cavitand

Abstract: A super aryl-extended calix [4]pyrrole equipped with four oxazolo [4,5-b]pyrazinyl units at its upper rim is reported. Its Pt II /Pd II -metallobridged cavitand counterparts were obtained by treatment with 2 equiv of cis-protected metal corners, [M(dppp)(OTf) 2 ] (dppp = 1,3-(bis-diphenylphosphino)propane). The metal corners arranged their axial phenyl substituents near the aromatic walls of the cavitand leading to the formation of inclusion complexes as single conformers. We characterized the inclusion comple… Show more

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