A direct one-step preparation of bis(dinitrogen) complexes of molybdenum(0) from molybdenum(V) chloride

George, T. Adrian; Noble, Mark E.

doi:10.1021/ic50184a065

Cited by 54 publications

(23 citation statements)

References 14 publications

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“…The solvents were dried and freshly distilled under inert gas. The imidazolium salts PCP*HCl,28, 50 and the molybdenum precursors [MoCl 3 (thf) 3 ],51 [MoBr 3 (thf) 3 ],52 [MoI 3 (thf) 3 ],53 trans ‐[Mo(N 2 ) 2 (PPh 2 Me) 4 ] ( 1 ),35, 54 and [MoCl 3 (dpepp)]55 have been prepared using the literature procedure. IR spectra were recorded on a Bruker Alpha‐P ATR‐IR Spectrometer.…”

Section: Methodsmentioning

confidence: 99%

CaO‐Based CO₂ Sorbents: From Fundamentals to the Development of New, Highly Effective Materials

2013

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The enormous anthropogenic emission of the greenhouse gas CO2 is most likely the main reason for climate change. Considering the continuing and indeed growing utilisation of fossil fuels for electricity generation and transportation purposes, development and implementation of processes that avoid the associated emissions of CO2 are urgently needed. CO2 capture and storage, commonly termed CCS, would be a possible mid-term solution to reduce the emissions of CO2 into the atmosphere. However, the costs associated with the currently available CO2 capture technology, that is, amine scrubbing, are prohibitively high, thus making the development of new CO2 sorbents a highly important research challenge. Indeed, CaO, readily obtained through the calcination of naturally occurring limestone, has been proposed as an alternative CO2 sorbent that could substantially reduce the costs of CO2 capture. However, one of the major drawbacks of using CaO derived from natural sources is its rapidly decreasing CO2 uptake capacity with repeated carbonation-calcination reactions. Here, we review the current understanding of fundamental aspects of the cyclic carbonation-calcination reactions of CaO such as its reversibility and kinetics. Subsequently, recent attempts to develop synthetic, CaO-based sorbents that possess high and cyclically stable CO2 uptakes are presented.

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Section: Methodsmentioning

confidence: 99%

CaO‐Based CO₂ Sorbents: From Fundamentals to the Development of New, Highly Effective Materials

2013

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“…For related literature, see: Alias et al (1997); Bruno et al (2002); Chatt & Dilworth (1977); George & Noble (1978); Mersmann et al (2006).…”

Section: Related Literaturementioning

confidence: 99%

Chloridobis[1,2-bis(diphenylphosphino)ethane](ethylimido)molybdenum(IV) tetraphenylborate acetonitrile disolvate

2007

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“…The synthetic route described in this paper was thus largely inspired by the initial work of Chatt and Dilworth [26] with some modifications developed in the group of Pickett. [27] For the synthesis of Mo(N 2 ) 2 (depe) 2 (1) we applied the procedure described by George and Noble [28] which utilizes the reduction of MoCl 5 with sodium amalgam followed by the addition of the phosphane ligand under dinitrogen. The bis(dinitrogen) species 1 was obtained in 69 % yield and characterized by an X-ray diffraction study (crystallographic data for 1 in the Supporting Information).…”

Section: Hydrido Nitrido Complexesmentioning

confidence: 99%

Hydride Transfer Reactivity of Mo(L)(H)(depe)₂ (L = N, NBEt₃)

et al. 2006

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Starting from Mo(N 2 ) 2 (depe) 2 (1), the nitrido complex Mo(N)-(N 3 )(depe) 2 (2) was obtained by the reaction of 1 with Me 3 -SiN 3 . Subsequent reaction of 2 with HCl in CH 3 OH afforded the cationic imido chloride 3, which could be converted into the nitrido chloride 4 with sodium bis(trimethylsilyl)amide. From 3 and 4 the hydrido complexes of the type Mo(H)(L)-(depe) 2 [L = N (7), NBEt 3 (8)] were obtained by the reaction with the hydride reagents LiBH 4 and NaHBEt 3 . The hydridic character of the L n M-H bond of 8 was determined by DQCC measurements (bond ionicity i = 81 %). Hydride reactivity studies were carried out on 7 and 8; however, only 8 underwent hydride transfer reactions. 8 reacted with 4,4Ј-dichlorobenzophenone and acetophenone to afford the correspond-

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A direct one-step preparation of bis(dinitrogen) complexes of molybdenum(0) from molybdenum(V) chloride

Cited by 54 publications

References 14 publications

CaO‐Based CO₂ Sorbents: From Fundamentals to the Development of New, Highly Effective Materials

CaO‐Based CO₂ Sorbents: From Fundamentals to the Development of New, Highly Effective Materials

Chloridobis[1,2-bis(diphenylphosphino)ethane](ethylimido)molybdenum(IV) tetraphenylborate acetonitrile disolvate

Hydride Transfer Reactivity of Mo(L)(H)(depe)₂ (L = N, NBEt₃)

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A direct one-step preparation of bis(dinitrogen) complexes of molybdenum(0) from molybdenum(V) chloride

Cited by 54 publications

References 14 publications

CaO‐Based CO2 Sorbents: From Fundamentals to the Development of New, Highly Effective Materials

CaO‐Based CO2 Sorbents: From Fundamentals to the Development of New, Highly Effective Materials

Chloridobis[1,2-bis(diphenylphosphino)ethane](ethylimido)molybdenum(IV) tetraphenylborate acetonitrile disolvate

Hydride Transfer Reactivity of Mo(L)(H)(depe)2 (L = N, NBEt3)

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Product

Resources

About

CaO‐Based CO₂ Sorbents: From Fundamentals to the Development of New, Highly Effective Materials

CaO‐Based CO₂ Sorbents: From Fundamentals to the Development of New, Highly Effective Materials

Hydride Transfer Reactivity of Mo(L)(H)(depe)₂ (L = N, NBEt₃)