This chapter provides a comprehensive overview of the principles of digital predistortion (DPD) linearization, a crucial technique for enhancing the performance of radiofrequency power amplifiers (PAs). The chapter delves into the inherent trade‐off between linearity and efficiency in PAs, highlighting the challenges of maintaining both high efficiency and linearity in wireless communication systems. It explores various power amplifier behavioral models and the methods used for parameter identification. The chapter also discusses the learning approaches employed for the parameter identification of the DPD, focusing on how they optimize the predistortion process. Regularization techniques, which are crucial for preventing overfitting and improving modeling performance, are examined in detail. Additionally, an overview of feature selection and feature extraction techniques is provided, emphasizing their importance in enhancing the accuracy and efficiency, in terms of computational complexity, of DPD algorithms. By integrating these topics, the chapter offers a detailed guide to understanding and implementing DPD linearization, making it a valuable resource for researchers and engineers working to cope with the inherent PA trade‐off between linearity and power efficiency in modern communication systems.