“…Radiative thermal management, particularly for passive radiative cooling (PRC) and passive radiative heating (PRH) without additional energy input, has drawn increasing attention in academia and industries as an alternative for traditional energy-intensive cooling/heating approaches. − PRC uses cold outer space (∼3 K) as the ultimate heat sink for the earth through the transparent atmospheric window (i.e., 8–13 μm). , For all-day PRC, particularly in the daytime, high emissivity within the atmospheric window and high solar reflection within the solar spectrum (i.e., 0.3–2.5 μm) of materials are synchronously anticipated to realize net cooling power under direct solar irradiation . Various material morphologies (e.g., film, − coating, , textile, and aerogel) and material structures (e.g., multilayer structure, , metamaterial structure, , randomly distributed particle, , and porous structure , ) have been developed to realize efficient all-day PRC.…”