“…2,6-dimethylaniline, 2,6-diethylaniline, and 2,6diisopropylaniline 3(d-f) were isolated in 67%, 40%, 42% yields, respectively as expected (Table 1, entry 4-6) [6]. All known products showed an identical melting point and NMR spectra to those in the literature (See Supplementary Material) [4]. a Reaction conditions: TBN (0.30 mL,~2.3 mmol), aniline derivatives 1(a-l) (2.0 mmol), glacial acetic acid (0.12 mL, 2.1 mmol), Sac-H (0.37 g, 2.0 mmol), TEAI (0.52 g, 2.0 mmol), solvent (H2O/EtOH 1:1 v/v, 5 mL); total reaction time (2 h).…”