A Facile Procedure for the Conversion of Oximes to Ketones and Aldehydes by the Use of Jones Reagent Adsorbed on Kieselguhr Reagent

Lou, Ji‐Dong; Lin, Fang; Lu, Xiu Lian; Wang, Qiang; Zou, Xiao-Nan

doi:10.1080/15533174.2011.609861

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Metal-mediated Reactions Of the Oxime Group1

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“…Aromatic, vinylic, and aliphatic oximes 178 were transformed to the corresponding aldehydes and ketones 179 in CH 2 Cl 2 at RT for 1.5–2 h in the presence of the Jones reagent (CrO 3 ·H 2 SO 4 ; 2 equiv) absorbed on silica . Carbonyl compounds 179 were isolated in 84–93% yields.…”

Section: Metal-mediated Reactions Of the Oxime Groupmentioning

confidence: 99%

Metal-Involving Synthesis and Reactions of Oximes

et al. 2017

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This review classifies and summarizes the past 10-15 years of advancements in the field of metal-involving (i.e., metal-mediated and metal-catalyzed) reactions of oximes. These reactions are diverse in nature and have been employed for syntheses of oxime-based metal complexes and cage-compounds, oxime functionalizations, and the preparation of new classes of organic species, in particular, a wide variety of heterocyclic systems spanning small 3-membered ring systems to macroheterocycles. This consideration gives a general outlook of reaction routes, mechanisms, and driving forces and underlines the potential of metal-involving conversions of oxime species for application in various fields of chemistry and draws attention to the emerging putative targets.

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Section: Metal-mediated Reactions Of the Oxime Groupmentioning

confidence: 99%