Solvent extraction IFuelreprocessinglCentrifugal contactors! Ruthenium jZirconiumThe contactor was also tested for application to the Civex and Thorex processes.
SummaryA miniature short-residence-time centrifugal solvent extraction contactor and an eight-stage laboratory minibank of centrifugal contactors were used for testing the possibility of utilizing kinetic effects for improving the Separation of uranium from ruthenium and zirconium in the Purex process. Results of these tests showed that a small improvement found in ruthenium and zirconium decontamination in single-stage solvent extraction tests was lost in the multistage extraction tests -in fact, the extent of Saturation of the solvent by uranium, rather than the stage residence time, controlled the extent of ruthenium and zirconium extraction. In applying the centrifugal contactor to the Purex process, the primary advantages would be less radiolytic damage to the solvent, high throughput, reduced solvent inventory, and rapid attainment of steady-state operating conditions. The multistage mini contactor was also tested to determine the suitability of short-residence-time contactors for use with the Civex and Thorex processes and was found to be compatible with the requirements of these processes.